Potentiometric study of equilibrium constants of a novel Triazine-Thione derivative and its stability constants with Hg2+, Cu2+, Ni2+, Pb2+ and Zn2+ metal ions in ethanol-water mixed.
Yazarlar (4)
Prof. Dr. Fatih POLAT
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Hayati SARI
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Firat Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
|
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Turkish Journal of Chemistry |
| Dergi ISSN | 1300-0527 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2013 |
| Cilt No | 37 |
| Sayı | 3 |
| Sayfalar | 439 / 448 |
| DOI Numarası | 10.3906/kim-1207-55 |
| Makale Linki | https://doi.org/10.3906/kim-1207-55 |
| Özet |
| The deprotonation constants of 5-hydroxy-5,6-di-pyridin-2-yl-4,5-dihydro- 2H-[1,2,4] triazine-3-thione (HPT) and the stability constants of its Hg 2+, Ni2+, Cu2+, Pb2+, and Zn 2+ ion complexes were studied in 20% ethanol and water mixed at 25 ± 0.1 °C and ionic strength (I) of 0.1 M supported by NaCl. Four pKa values of HPT were determined: 3.58, 6.30, 9.23, and 9.69. In various pH conditions, the different complex forms were formulated as ML, MHL, MH2 L, MH3 L, MH4 L, and MH-2L between Hg2+, Ni2+, Cu2+, Pb2+ , and Zn2+ ions and HPT. According to the potentiometric and spectrophotometric results, the HPT and Hg2+ combination formed a selective and highly stable complex at pH 7. © TÜBITAK. |
| Anahtar Kelimeler |
| Equilibrium constants | Potentiometry | Proton affinity | Triazine-thione |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 8 |
| SCOPUS | 8 |
| TRDizin | 1 |
| Google Scholar | 11 |