Surface characterization and electroanalytical applications of the newly developed copper(II)-selective potentiometric sensor        
Yazarlar (3)
Doç. Dr. Oğuz ÖZBEK Zonguldak Bülent Ecevit Üniversitesi, Türkiye
Onur Cem Altunoluk
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Analytical Sciences
Dergi ISSN 0910-6340 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q3
Makale Dili İngilizce
Basım Tarihi 01-2024
Cilt No 40
Sayı 1
Sayfalar 141 / 149
DOI Numarası 10.1007/s44211-023-00436-z
Makale Linki http://dx.doi.org/10.1007/s44211-023-00436-z
Özet
In this work, we developed a new copper(II)-selective potentiometric sensor and investigated its surface with scanning electron microscopy (SEM). Besides the surface images of the sensors conditioned in copper(II) solutions, energy–dispersive X-ray (EDX) and mapping studies were carried out. According to the results obtained, it was determined that copper(II) ions adhered to the porous areas on the sensor surface, and that Cu2+ ions showed a wide distribution on the sensor surface in mapping studies. The new sensor had a Nernstian response of 29.3 ± 0.5 mV/decade in the concentration range of 1.0 × 10−1–1.0 × 10−5 M and a low detection limit of 8.56 × 10−6 M. The proposed sensor had fast response time (< 10 s), wide pH working range (5.0–10.0), good repeatability and stability. Finally, the sensor performed the determination of copper(II) ions in various water samples with very high recoveries (96.0–102.0%). Graphical abstract: [Figure not available: see fulltext.].
Anahtar Kelimeler
Copper | Heavy metal | Scanning electron microscopy | Sensor