Potentiometric study of equilibrium constants of a novel triazine thione derivative and its stability constants with Hg2 Cu2 Ni2 Pb2 and Zn2 metal ions in ethanol and water mixed
Yazarlar (4)
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Turkish Journal of Chemistry |
| Dergi ISSN | 1300-0527 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 07-2013 |
| Cilt No | 37 |
| Sayı | 3 |
| Sayfalar | 439 / 448 |
| DOI Numarası | 10.3906/kim-1207-55 |
| Makale Linki | http://journals.tubitak.gov.tr/chem/ |
| Özet |
| The deprotonation constants of 5-hydroxy-5,6-di-pyridin-2-yl-4,5-dihydro-2H-[1,2,4] triazine-3-thione (HPT) and the stability constants of its $Hg^{2+},Cu^{2+},Ni^{+2},Pb^{2+},$ and $Zn^{2+}$ ion complexes were studied in 20% ethanol and water mixed at 25 ± 0.1 ◦C and ionic strength (I) of 0.1 M supported by NaCl. Four pKa values of HPT were determined: 3.58, 6.30, 9.23, and 9.69. In various pH conditions, the different complex forms were formulated as ML, MHL, $MH_2$ L, $MH_3$ L, $MH_4$ L, and $MH_{-2}$L between $Hg^{2+},Ni^{2+},Cu^{+2},Pb^{2+},$ and $Zn^{2+}$ ions and HPT. According to the potentiometric and spectrophotometric results, the HPT and $Hg^{2+}$ combination formed a selective and highly stable complex at pH 7. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| TRDizin | 1 |