Selective determination of Cr(III) ions with novel potentiometric electrodes
Yazarlar (4)
Prof. Dr. Ömer IŞILDAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Oğuz ÖZBEK
Zonguldak Bülent Ecevit Üniversitesi, Türkiye
Doç. Dr. İlyas YILDIZ
Iğdır Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
|
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of the Chinese Chemical Society |
| Dergi ISSN | 0009-4536 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2023 |
| Cilt No | 70 |
| Sayı | 9 |
| Sayfalar | 1814 / 1820 |
| DOI Numarası | 10.1002/jccs.202300165 |
| Makale Linki | http://dx.doi.org/10.1002/jccs.202300165 |
| Özet |
| Background: Ionophores in the composition of potentiometric ion-selective electrodes interact directly with the analyte ion and enable the determination of ionic species in various samples. Objectives: In this study, a novel ion-selective electrode based on 5-bromosalicylaldehyde thiosemicarbazone was developed for the selective determination of Cr3+ ions. Methods: The optimum electrode composition contained ionophore, poly (vinyl chloride) (PVC), bis (2-ethylhexyl) sebacate (BEHS) and potassium tetrakis (p-chlorophenyl) borate (KTpClPB) in ratios of 4.0: 61.0: 34.0: 1.0 (mg), respectively. Potential measurements were performed using a computer-controlled multi-channel potentiometric measurement system. Results: The developed Cr (III)-selective electrode exhibited a low detection limit of 3.96 × 10−6 M over a wide concentration range of 1.0 × 10−5 – 1.0 × 10−1 M (R2: 0.9979). The electrode exhibited good selectivity towards Cr3+ ions among metal ions with different charges. The chromium (III)-selective electrode, which exhibited highly reproducible results in three different concentration ranges, also had a very fast response time of 5 s. Conclusions: The developed Cr (III)-selective electrode were successfully performed in various beverage samples. As a result, the proposed electrode can be an alternative to other analytical methods in the analysis of Cr3+ ions. |
| Anahtar Kelimeler |
| chromium(III) | ion-selective electrodes | potentiometry | thiosemicarbazone |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 1 |
| Google Scholar | 2 |