Eco-friendly C60-SESMP-Fe3O4 inorganic magnetizable nanocomposite as high-performance adsorbent for magnetic removal of arsenic from crude oil and water samples
Yazarlar (7)
Tikrit University, Irak
Imam Ja'afar Al-Sadiq University, Irak
Tikrit University, Irak
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tikrit University, Irak
Doç. Dr. Hüseyin AKBAŞ
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ankara Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Materials Chemistry and Physics |
| Dergi ISSN | 0254-0584 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q2 |
| Makale Dili | İngilizce |
| Basım Tarihi | 06-2019 |
| Cilt No | 231 |
| Sayı | 1 |
| Sayfalar | 292 / 300 |
| DOI Numarası | 10.1016/j.matchemphys.2019.04.040 |
| Makale Linki | https://doi.org/10.1016/j.matchemphys.2019.04.040 |
| Özet |
| Fullerene biopolymer-magnetite nano inorganic composite is produced from newly prepared fullerene (C60)soluble eggshell membrane protein (SESMP)composite mixed with Fe3O4NPs. UV–Vis, FTIR, VSM, SEM, EDX and STEM are demonstrated that a stable Fe3O4 can be retained on the surface of C60-ESMP bio nanocomposite by a multi-step chemical reaction. The resulting eco-friendly C60-ESMP-Fe3O4 nano inorganic composite was screened for its magnetic solid phase extraction (MSPE)performance of arsenic in six crude oil and water samples using ICP-OES technique. The pH, eluent type, concentration and volume, standing, elution and sedimentation times, sample volume, C60-SESMP-Fe3O4 mass, interfering ions and reusability of the prepared nanocomposite have been examined. The optimal conditions were experimentally investigated to be pH = 8, sample volume = 50 mL and C60-SESMP-Fe3O4 mass = 20 mg with an enrichment factor of 20. The results of reuse were excellent, showing high reusability, which were 20 MSPE runs with only 0.2–1% error. The limits of detection (LOD)were found to be 0.0473 and 0.0325 ng. mL−1 for As(III)and As(V), respectively. Subsequently, relative standard deviations (RSD%)were determined as 1.15% for As(III)and 1.31% for As(V). These results indicate that this stable nanocomposites system would be an excellent candidate for removal of As(III)and As(V)rapidly from crude oil and water with the ability of reuse. |
| Anahtar Kelimeler |
| Arsenic | Eggshell membrane protein | Fe O 3 4 | Fullerene | Magnetic SPE |
Science Direct
Eco-friendly C60-SESMP-Fe3O4 inorganic magnetizable nanocomposite as high-performance adsorbent for magnetic removal of arsenic from crude oil and water samples
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 71 |
| SCOPUS | 96 |