Novel Hg(II) and Pd(II) benzotriazole (Hbta) complexes: Synthesis, characterization, X-ray crystal structure of [Pd(PPh3)(μ-bta)Cl]2. DMSO and thermodynamic study of their H2 storage
Yazarlar (6)
Tikrit University, Irak
Tikrit University, Irak
Tikrit University, Irak
Al-Hadi University College, Irak
Doç. Dr. Hüseyin AKBAŞ
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Molecular Structure |
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2020 |
| Cilt No | 1207 |
| Sayı | 1 |
| Sayfalar | 127832 / 0 |
| DOI Numarası | 10.1016/j.molstruc.2020.127832 |
| Makale Linki | https://doi.org/10.1016/j.molstruc.2020.127832 |
| Özet |
| Benzotriazole (Hbta) complexes with Hg(II) and Pd(II) of the types: [Hg(bta)2] (1), [Hg(bta)2(diphos)]; diphos = dppe (2), dppp (3) or dppb (4), [Hg(bta)2(PPh3)2] (5), [Pd(Hbta)2Cl2] (6), [Pd(bta)Cl]2 (7) and [PdCl(bta)(PPh3)]2.DMSO (8) were prepared and characterized by elemental analyses, conductivity measurements, infrared, 1H- and 31P-{1H} NMR spectra. [Pd(PPh3)(μ-bta)Cl]2. DMSO (8) was structurally characterized by single-crystal X-ray diffraction. Structural information exposed that benzotriazole acts as a bidentate bridging ligand bonded through the deprotonated nitrogen and the neutral nitrogen atoms. The hydrogen storage ability of complexes (1–4) was studied after detecting their BET surface area. The results show that complex (1) is able to store 3.35 wt% physically at 77 K under 120 bar. |
| Anahtar Kelimeler |
| Benzotriazole | Complexes | H storage 2 | Hg(II) | Pd(II) | Phosphine |
Science Direct
Novel Hg(II) and Pd(II) benzotriazole (Hbta) complexes: Synthesis, characterization, X-ray crystal structure of [Pd(PPh3)(μ-bta)Cl]2. DMSO and thermodynamic study of their H2 storage
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 36 |
| SCOPUS | 46 |