Synthesis and Sensor Properties of a Phenol Derivative Molecule: Potentiometric Determination of Silver(I) Ions
Yazarlar (4)
Doç. Dr. Oğuz ÖZBEK
Zonguldak Bülent Ecevit Üniversitesi, Türkiye
Zonguldak Bulent Ecevit University, Türkiye
Prof. Dr. Esra KOÇ
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Electrocatalysis |
| Dergi ISSN | 1868-2529 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 07-2022 |
| Cilt No | 13 |
| Sayı | 4 |
| Sayfalar | 486 / 493 |
| DOI Numarası | 10.1007/s12678-022-00738-2 |
| Makale Linki | http://dx.doi.org/10.1007/s12678-022-00738-2 |
| Özet |
| Herein, we developed a novel potentiometric sensor that exhibits high selectivity towards Ag+ ions, using a newly synthesized phenol derivative (4) molecule as an electroactive material (ionophore). The sensor was prepared by coating the surface of a conductive solid contact by a membrane containing bis(2-ethylhexyl)sebacate (BEHS) as plasticizer, poly (vinly chloride) (PVC) as a polymeric matrix, electroactive material (4), and potassium tetrakis(4-chlorophenyl)borate (KTpClPB) as an additive. The developed sensor exhibited a wide linear concentration range of 1.0 × 10–6–1.0 × 10−1 mol L−1 and a lower detection limit of 5.87 × 10−7 mol L−1. The sensor exhibited quite good selectivity over other cationic species, and its potential response remained unaffected of pH in the range of 3.0–7.0. In addition, the developed sensor had a short response time of 8 s, good repeatability, and stability. Finally, the proposed sensor was used in the direct determination of Ag+ in different water samples, and as an indicator electrode for the end point determination in the potentiometric titration of Ag+ ions against sodium chloride. Graphical abstract: [Figure not available: see fulltext.]. |
| Anahtar Kelimeler |
| Phenol derivatives | Potentiometry | Sensor | Silver(I) | Synthesis |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 23 |
| SCOPUS | 28 |
| Google Scholar | 30 |