Synthesis and Isolation of 1 cyclohex 1 2 dien 1 ylbenzene from 1 2 iodocyclohex 1 en 1 yl benzene and 1 2 iodocyclohex 2 en 1 yl benzene
Yazarlar (5)
Prof. Dr. Mustafa CEYLAN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Yakup BUDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Meliha Burcu GÜRDERE Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Irfan Ozdemir Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Öğr. Gör. Esra Findik Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Turkish Journal of Chemistry (Q4) | ||
| Dergi ISSN | 1300-0527 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2007 |
| Cilt / Sayı / Sayfa | 31 / 6 / 647–657 | DOI | – |
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| The key compounds, 1-(2-iodocyclohex-1-en-1-yl) benzene (12) and 1-(2-iodocyclohex-2-en-1-yl) benzene (13), for the generation of 1-cyclohex-1, 2-dien-1-ylbezene (20) were synthesized starting with cyclohexanone. Separate reactions of 12 and 13 with KOtBu in benzene in a sealed tube at 180 C gave 6 products: 1-cyclohex-1-en-1-ylbenzene (8), 2-phenylcyclohexanone (10), 1, 8-diphenyl-2, 3, 4, 4a, 4b, 5, 6, 7-octahydrobiphenylene (21), 8a-phenyl-1, 2, 3, 4, 6, 7, 8, 8a-octahyd-rotriphenylene (22), 1, 2-diphenylcyclohexene (23), and 1-(2-tert-butoxycyclohex-1-enyl) benzene (24). In addition, reactions of 12 and 13 under the same conditions in the presence of diphenylisobenzofuran and furan as trapping reagents afforded the [4+ 2] cyclo-adducts 30, 31, and 32 in good yields, respectively. |
| Anahtar Kelimeler |
| Cyclic strained allenes | Cycloaddition | Dehydroiodination | Dimerisation |
