Synthesis of 1 phenyl 1 2 cyclohexadiene and 1 2 bromocyclohex 2 en 1 yl benzene and Wurtz like condensation products in the reaction of 1 2 3 dibromocyclohex 1 en 1 yl benzene with zinc
Yazarlar (2)
Prof. Dr. Mustafa CEYLAN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Yakup BUDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Chemical Research Part S (Q4)
Dergi ISSN 0308-2342
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 01-2002
Cilt / Sayı / Sayfa 9 / 9 / 416–419 DOI 10.3184/030823402103172716
UAK Araştırma Alanları
Organik Kimya
Özet
The base-catalysed elimination of 1-(2-bromocyclohex-2-en-1-yl)benzene 1 and the zinc-catalysed elimination of 1-(2,3-dibromocyclohex-1-en-1-yl)benzene 9 have been used for the synthesis of 1-phenyl-1,2-cyclohexadiene 2; reaction of 9 with zinc in THF resulted in the formation of two isomeric Wurtz-like condensation products 3 and 4, but the reaction of 1 with t-BuOK gave the allene 2.
Anahtar Kelimeler
1-(2,3-dibromocyclohex-1-en-1-yl) benzene | 1-(2-bromocyclohex-2-en-1-yl) benzene | 1-phenyl-1,2-cyclohexadiene | Zinc