Dissipation behaviors of deltamethrin, emamectin benzoate and hexythiazox in grape under field conditions
Yazarlar (3)
Doç. Dr. Tarık BALKAN
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Adem YAĞCI
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Kenan KARA
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Environmental Science and Health Part B Pesticides Food Contaminants and Agricultural Wastes |
| Dergi ISSN | 0360-1234 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | Türkçe |
| Basım Tarihi | 01-2024 |
| Cilt No | 59 |
| Sayı | 3 |
| Sayfalar | 123 / 129 |
| DOI Numarası | 10.1080/03601234.2024.2308487 |
| Makale Linki | http://dx.doi.org/10.1080/03601234.2024.2308487 |
| Özet |
| The objective of this study was to evaluate the dissipation kinetics of deltamethrin, emamectin benzoate, and hexythiazox in grapes. The QuEChERS method was employed and validated for the precise determination of these three pesticides using liquid chromatography–tandem mass spectrometry (LC–MS/MS). Excellent linearity was observed with regression coefficients exceeding 0.998. Notably, the limits of quantification (LOQ) were significantly lower than the maximum residue limits (MRLs) established for grapes by the European Union. The QuEChERS method l recovered 93.23% of the pesticides with an acceptable RSD of 5.35% (n = 180), demonstrating its suitability for quantifying them in grapes. Half-lives of deltamethrin, emamectin benzoate, and hexythiazox in grapes were 2.62-2.68 days, 8.15-7.30 days, and 3.24-4.01 days, respectively, for both single and double doses. Residues of all pesticides fell below the MRLs by the preharvest interval. This suggests that their application can be considered safe for grapes, ensuring both pest control and consumer safety. |
| Anahtar Kelimeler |
| Degradation rate | grape cultivation | LC–MS/MS | method validation | pesticide residue |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 6 |
| SCOPUS | 5 |
| Google Scholar | 7 |