Synthesis, characterization and sensor applications of a new 1,4–naphthoquinone derivative molecule      
Yazarlar (4)
Doç. Dr. Oğuz ÖZBEK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Onur Cem Altunoluk
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Kıymet BERKİL AKAR Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Chemical Papers
Dergi ISSN 0366-6352 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q3
Makale Dili İngilizce
Basım Tarihi 05-2025
Cilt No 79
Sayı 5
Sayfalar 3249 / 3260
DOI Numarası 10.1007/s11696-025-04002-x
Makale Linki http://dx.doi.org/10.1007/s11696-025-04002-x
Özet
In this study, a new naphthoquinone derivative molecule was synthesized with a very high yield (99.0%), and its sensor properties were investigated. The characterization of the synthesized molecule was carried out using spectroscopic methods such as 1H-, 13C-NMR and FT-IR. Polymer membrane potentiometric sensors were prepared using this molecule as an ionophore, and these newly prepared sensors exhibited selective behavior toward barium(II) ions. The one of barium(II)-selective potentiometric sensors developed had a low detection limit of 3.51 × 10−6 mol L−1 in a wide concentration range of 1.0 × 10−1–1.0 × 10−5 mol L−1 and had also a near-Nernstian behavior. The proposed barium(II) selective sensor was shown to have good reproducibility, fast response time (< 5 s), wide pH working range (5.0–10.0) and low cost production. Besides, it could detect barium(II) ions in various water samples with high recoveries; and based on its advantages, it can be proposed as a new alternative in the analysis of barium(II) ions.
Anahtar Kelimeler
Barium(II) | Ion-selective electrodes | Naphthoquinones | Potentiometry | Synthesis