Potentiometric PVC membrane ion–selective electrode for the determination of Sr(II) ions      
Yazarlar (1)
Doç. Dr. Oğuz ÖZBEK Zonguldak Bulent Ecevit University, Türkiye
Makale Türü Açık Erişim Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayınlanan tam makale
Dergi Adı Sensors International
Dergi ISSN 2666-3511 Scopus Dergi
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce
Basım Tarihi 06-2022
Cilt No 3
Sayı 1
Sayfalar 100185 /
DOI Numarası 10.1016/j.sintl.2022.100185
Makale Linki https://doi.org/10.1016/j.sintl.2022.100185
Özet
In this study, an ion–selective electrode was developed for the potentiometric determination of strontium ions. Membrane optimization studies showed that the most suitable membrane composition was 4.0% (w/w) synthesized ionophore, 63.0% (w/w) bis(2–ethylhexyl)sebacate (BEHS), 32.0% (w/w) poly(vinyl chloride; PVC) and 1.0% (w/w) potassium tetrakis(p–chlorophenyl)borate (KTpClPB) in terms of potentiometric performance characteristics. The electrode, which exhibits a stable potentiometric behaviour, shows a linear response in the concentration range of 1.0 ​× ​10−5 – 1.0 ​× ​10−1 ​mol ​L−1 ​(R2 ​= ​0.998). The electrode has a detection limit of 7.94 ​× ​10−6 ​mol ​L−1 and a fast response time of 7s. The electrode exhibits selectivity against Sr(II) ions in the presence of some cationic species and works without being affected by pH changes in the pH range of 6.0–9.0. The proposed electrode …
Anahtar Kelimeler
Ion–selective electrode | Potentiometry | PVC membrane | Strontium