Effect of Bismuth on hydrogen storage properties of melt-spun LaNi4.7-x Al0.3Bix (x = 0.0, 0.1, 0.2, 0.3) ribbons    
Yazarlar (4)
Prof. Dr. Fikret YILMAZ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Semra ERGEN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Soon Jık Hong
Kongju National University, Güney Kore
Orhan Uzun
Ankara Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı International Journal of Hydrogen Energy
Dergi ISSN 0360-3199 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 11-2018
Cilt No 43
Sayı 44
Sayfalar 20243 / 20251
DOI Numarası 10.1016/j.ijhydene.2018.07.090
Makale Linki http://dx.doi.org/10.1016/j.ijhydene.2018.07.090
Özet
The LaNi5 intermetallic compound is an AB5 type hydrogen storage alloy which exhibits low operating temperature, easy activation, low pressure and tolerance to impurities. In this study, LaNi4.7-x Al0.3Bix (x = 0.0, 0.1, 0.2, 0.3) alloys were produced by melt-spinning technique and the effects of Al and Bi additions on the microstructure, thermal and hydrogen storage properties of LaNi5 were investigated. The results showed that substitution of Ni with Al led to a desired decrease in absorption/desorption plateau pressure and hysteresis without a decrease in hydrogen storage capacity. In contrast, Bi substitution with Ni increased the absorption/desorption plateau pressure, reduced the hydrogen capacity and increased pulverization resistance of the alloy due to the formation of BiLa and AlNi3 intermetallic phases at the grain boundaries.
Anahtar Kelimeler
AB type hydride 5 | Hydrogen storage | Melt-spinning