Surface characterization of barium(II)-selective potentiometric sensor based on a newly synthesized thiosemicarbazone derivative molecule        
Yazarlar (5)
Onur Cem Altunoluk
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Oğuz ÖZBEK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Erbay Kalay
Kafkas Üniversitesi, Türkiye
Feyzi Sinan Tokalı
Kafkas Üniversitesi, Türkiye
Osman Nuri Aslan
Atatürk Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Electroanalysis
Dergi ISSN 1040-0397 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q3
Makale Dili İngilizce
Basım Tarihi 06-2024
Cilt No 36
Sayı 7
Sayfalar 202300407 / 0
DOI Numarası 10.1002/elan.202300407
Makale Linki http://dx.doi.org/10.1002/elan.202300407
Özet
In this study, we synthesized a new thiosemicarbazone derivative molecule (5) that exhibits sensor properties. The characterization of the synthesized molecule was performed using spectroscopic methods such as 1H−, 13C–NMR, FT–IR and Q–TOF. PVC-membrane ion-selective sensors were prepared in which the synthesized molecule was used as an ionophore. Surface images of the prepared sensors were examined by scanning electron microscope (SEM) technique. The prepared sensors exhibited selectivity towards barium(II) ions. The developed barium(II)-selective sensor had a low detection limit of 5.54×10−7 M in the concentration range of 1.0×10−1–1.0×10−6 M. The proposed barium(II)-selective sensor had fast response time, good repeatability and stability, and can be manufactured with low cost. The sensor can detect barium(II) ions in various water samples with very high recoveries.
Anahtar Kelimeler
barium(II) | ion-selective electrodes | sensor | synthesis | thiosemicarbazone