A bromide-⁠selective PVC membrane potentiometric sensor      
Yazarlar (3)
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Oğuz ÖZBEK Zonguldak Bulent Ecevit University, Türkiye
K. M. Yigit
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayınlanan tam makale
Dergi Adı Bulgarian Chemical Communications
Dergi ISSN 0861-9808 Scopus Dergi
Dergi Tarandığı Indeksler Scopus
Makale Dili İngilizce
Basım Tarihi 12-2020
Cilt No 52
Sayı 4
Sayfalar 448 / 452
DOI Numarası 10.34049/bcc.52.4.5235
Makale Linki https://doi.org/10.34049/bcc.52.4.5235
Özet
In this study, a novel poly(vinyl chloride) membrane bromide-selective sensor was developed. The best performance was obtained with a membrane composition of 2.0% ionophore, 33.0% poly(vinyl chloride) (PVC), 64.0% o-nitrophenyloctylether (o-NPOE) and 1.0% potassium tetrakis (p-chlorophenyl) borate (KTpClPB). The sensor exhibits linear potentiometric response towards bromide ion in the concentration range of 1.0×10-1 - 1.0×10-4 mol L-1 and has a detection limit of 2.2×10-5 mol L-1. The bromide-selective sensor has a fast response time of 10 s and displays a highly selective response towards bromide compared to different anions. The sensor can be used in the pH range from 4.0 to 10.0. Finally, the bromide-selective sensor was successfully used for the determination of bromide in purified and commercial drinking water.
Anahtar Kelimeler
All-solid-state | Bromide determination | Ion-selective electrode | Potentiometry | PVC membrane
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
SCOPUS 11
Google Scholar 16
A bromide-⁠selective PVC membrane potentiometric sensor

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