Electroanalytical Determination of Copper(II) Ions Using a Polymer Membrane Sensor
Yazarlar (4)
Doç. Dr. Oğuz ÖZBEK
Zonguldak Bülent Ecevit Üniversitesi, Türkiye
Prof. Dr. Meliha Burcu GÜRDERE
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Dr. Öğr. Üyesi Çağlar BERKEL
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
|
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Electrochemical Science and Technology |
| Dergi ISSN | 2093-8551 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 02-2023 |
| Cilt No | 14 |
| Sayı | 1 |
| Sayfalar | 66 / 74 |
| DOI Numarası | 10.33961/jecst.2022.00661 |
| Makale Linki | http://dx.doi.org/10.33961/jecst.2022.00661 |
| Özet |
| In this study, a new potentiometric sensor selective to copper(II) ions was developed and characterized. The developed sensor has a polymeric membrane and contains 4.0% electroactive material (ionophore), 33.0% poly(vinyl chloride) (PVC), 63.0% bis(2–ethylhexyl)sebacate (BEHS) and 1.0% potassium tetrakis(p–chlorophenyl)borate (KTpClPB). This novel cop-per(II)–selective sensor exhibits a Nernstian response over a wide concentration range from 1.0×10 to 1.0×10 mol L with a slope of 29.6 (±1.2) mV decade-1, and a lower detection limit of 8.75×10 mol L. The sensor,-6 which was pro-duced economically by synthesizing the ionophore in the laboratory, has a good selectivity and repeatability, fast response-1-1-7-1 time and stable potentiometric behaviour. The potential response of the sensor remains unaffected of pH in the range of 5.0–10.0. Based on the analytical applications of the sensor, we showed that it can be used as an indicator electrode in the quantification of Cu ions by potentiometric titration against EDTA, and can also be successfully utilized for the determination of copper(II) ions in2+ different real samples. |
| Anahtar Kelimeler |
| Copper(II) | Potentiometry | PVC membrane | Sensor | Trace elements |