Use of 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin as sensor material: potentiometric determination of aluminium(III) ions
Yazarlar (2)
Doç. Dr. Oğuz ÖZBEK
Zonguldak Bülent Ecevit Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Bulletin of Materials Science |
| Dergi ISSN | 0250-4707 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | Türkçe |
| Basım Tarihi | 06-2022 |
| Cilt No | 45 |
| Sayı | 3 |
| Sayfalar | 114 / 0 |
| DOI Numarası | 10.1007/s12034-022-02696-3 |
| Makale Linki | http://dx.doi.org/10.1007/s12034-022-02696-3 |
| Özet |
| In this study, 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin has been synthesized and used as an ionophore for the preparation of a poly(vinyl chloride) (PVC) membrane sensor for aluminium(III) ions. The optimum composition of the best performing membrane contained ionophore, bis(2-ethylhexyl) adipate, PVC and potassium tetrakis(p-chlorophenyl) borate in the ratio of 4.0:63.0:32.0:1.0 (mg). The prepared PVC membrane morphology has been analysed by scanning electron microscopy. The developed aluminium(III)-selective sensor works in a wide linear concentration range of 1.0 × 10–5 to 1.0 × 10–1 mol l–1 and, the detection limit of this sensor is 2.81 × 10−6 mol l–1. The sensor displays near-Nernstian slope of 25.0 ± 2.7 mV per decade for Al3+ ions. The aluminium(III)-selective sensor has a wide working pH range of 5.0–10.0. The sensor shows good reusability, long-term stability and a fast response time of less than 5 s. In addition, the sensor shows good selectivity for Al3+ ions over different cations. This aluminium(III)-selective sensor was successfully used as an indicator electrode in the potentiometric titration of Al3+ ions with EDTA. The developed sensor was successfully applied to the direct determination of Al3+ in different water samples. |
| Anahtar Kelimeler |
| ionophore | Porphyrins | potentiometry | PVC membrane | sensor |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 17 |
| SCOPUS | 17 |
| Google Scholar | 18 |