Highly Brominated Anthracenes as Precursors for The Convenient Synthesis of 2,9,10-Trisubstituted Anthracene Derivatives
Yazarlar (5)
Osman Cakmak Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Dr. Öğr. Üyesi Leyla AYDOĞAN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Kıymet BERKİL AKAR Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ilhami Gulcin Atatürk Üniversitesi, Türkiye
Orhan Buyukgungor Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Beilstein Journal of Organic Chemistry (Q3) | ||
| Dergi ISSN | 1860-5397 Dergi Bilgileri (2008) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2008 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 10-12-2008 |
| Cilt / Sayı / Sayfa | 4 / 1 / 1–8 | DOI | 10.3762/bjoc.4.50 |
| Makale Linki | https://www.beilstein-journals.org/bjoc/articles/4/50 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| When 9, 10-dibromoanthracene was treated with bromine in CCl 4 without a catalyst, 1, 2, 3, 4, 9, 10-hexabromo-1, 2, 3, 4-tetrahydroanthracene (3) was obtained in 95% yield in the absence of other stereoisomers or rearomatization products. We investigated the base-induced elimination reaction of hexabromide 3 under various conditions. Pyridine-induced elimination of hexabromide 3 afforded 2, 9, 10-tribromoanthracene (12) in 75% yield, and tribromide 12 was transformed to trimethoxy compound 13 and trinitrile 14 by copper-assisted nucleophilic substitution reactions. |
| Anahtar Kelimeler |
| Anthracene derivative | Bromination | Bromoanthracene | Cyanoanthracene | Methoxyanthracene |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Yöksis | 12 |
| Web of Science | 11 |
| Scopus | 9 |
| Google Scholar | 16 |