Highly Brominated Anthracenes as Precursors for The Convenient Synthesis of 2,9,10-Trisubstituted Anthracene Derivatives
Yazarlar (5)
Türkiye
Doç. Dr. Kıymet BERKİL AKAR
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Atatürk Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Beilstein Journal of Organic Chemistry |
| Dergi ISSN | 1860-5397 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2008 |
| Cilt No | 4 |
| Sayı | 50 |
| Sayfalar | 1 / 8 |
| DOI Numarası | 10.3762/bjoc.4.50 |
| Makale Linki | https://www.beilstein-journals.org/bjoc/articles/4/50 |
| Özet |
| When 9, 10-dibromoanthracene was treated with bromine in CCl 4 without a catalyst, 1, 2, 3, 4, 9, 10-hexabromo-1, 2, 3, 4-tetrahydroanthracene (3) was obtained in 95% yield in the absence of other stereoisomers or rearomatization products. We investigated the base-induced elimination reaction of hexabromide 3 under various conditions. Pyridine-induced elimination of hexabromide 3 afforded 2, 9, 10-tribromoanthracene (12) in 75% yield, and tribromide 12 was transformed to trimethoxy compound 13 and trinitrile 14 by copper-assisted nucleophilic substitution reactions. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 16 |