Bromination of 5-Methoxyindane: Synthesis of New Benzoindenone Derivatives and Ready Access to 7H-Benzo[c]fluoren-7-one Skeleton
Yazarlar (4)
Prof. Dr. Ahmet Tutar Sakarya Üniversitesi, Türkiye
Doç. Dr. Kıymet BERKİL AKAR Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Richard R Hark
Juniata College, Amerika Birleşik Devletleri
Metin Balcı Middle East Technical University (Metu), Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Synthetic Communications (Q4)
Dergi ISSN 0039-7911 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2008
Kabul Tarihi Yayınlanma Tarihi 01-01-2008
Cilt / Sayı / Sayfa 38 / 9 / 1333–1345 DOI 10.1080/00397910801916223
Makale Linki http://dx.doi.org/10.1080/00397910801916223
UAK Araştırma Alanları
Organik Kimya
Özet
The photobromination of 5‐methoxyindane and 5‐methoxyindanone was studied at both high and low temperatures. 1,2,3‐Tribromo‐6‐methoxyindene was easily synthesized by photolytic bromination of 5‐methoxyindane at low temperature. 1,1,2,3‐Tetrabromo‐6‐methoxyindene was obtained from the photobromination of 5‐methoxyindan at 77 °C, which could then be easily converted to the 2,3‐dibromo‐6‐methoxyindene by silver‐supported hydrolysis. Photochemical bromination of 5‐methoxy‐1‐indanone with N‐bromosuccinimide (NBS) gave 3‐bromo‐6‐methoxyindene, which upon thermolysis gave a benzo[c]fluorenone derivative.
Anahtar Kelimeler
Benzo[c]fluorenone | Indenone | Photobromination
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 14
Scopus 14
Google Scholar 23
Bromination of 5-Methoxyindane: Synthesis of New Benzoindenone Derivatives and Ready Access to 7H-Benzo[c]fluoren-7-one Skeleton

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