Bromination of 5-Methoxyindane: Synthesis of New Benzoindenone Derivatives and Ready Access to 7H-Benzo[c]fluoren-7-one Skeleton
Yazarlar (4)
Sakarya Üniversitesi, Türkiye
Doç. Dr. Kıymet BERKİL AKAR
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
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| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Synthetic Communications |
| Dergi ISSN | 0039-7911 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 04-2008 |
| Cilt No | 38 |
| Sayı | 9 |
| Sayfalar | 1333 / 1345 |
| DOI Numarası | 10.1080/00397910801916223 |
| Makale Linki | http://dx.doi.org/10.1080/00397910801916223 |
| Özet |
| The photobromination of 5‐methoxyindane and 5‐methoxyindanone was studied at both high and low temperatures. 1,2,3‐Tribromo‐6‐methoxyindene was easily synthesized by photolytic bromination of 5‐methoxyindane at low temperature. 1,1,2,3‐Tetrabromo‐6‐methoxyindene was obtained from the photobromination of 5‐methoxyindan at 77 °C, which could then be easily converted to the 2,3‐dibromo‐6‐methoxyindene by silver‐supported hydrolysis. Photochemical bromination of 5‐methoxy‐1‐indanone with N‐bromosuccinimide (NBS) gave 3‐bromo‐6‐methoxyindene, which upon thermolysis gave a benzo[c]fluorenone derivative. |
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BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 22 |