Functionalization of naphthalene: a novel synthetic route to brominated naphthoquinones
Yazarlar (3)
Osman Çakmak İstanbul Rumeli Üniversitesi, Türkiye
Doç. Dr. Kıymet BERKİL AKAR Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Nuri Kaplan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | ARKIVOC (Q4) | ||
| Dergi ISSN | 1551-7004 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2012 |
| Cilt / Sayı / Sayfa | 2012 / 7 / 274–281 | DOI | 10.3998/ark.5550190.0013.718 |
| Makale Linki | http://dx.doi.org/10.3998/ark.5550190.0013.718 | ||
| Özet |
| An efficient procedure is described for synthesis of 2, 5, 8-tribromonaphthoquinone (12) from naphthalene in four reaction steps. Silver-promoted solvolysis of hexabromide 3 produces the specific diastereostereoisomer 10. Dehydrobromination of 10 using sodium methoxide gives tribromodihydronaphthalene-1, 4-diol 11 in high yield. PCC oxidation of either 10 or 11 results in the formation of 2, 5, 8-tribromonaphthalene-1, 4-dione (12). |
| Anahtar Kelimeler |
| Bromonaphthalene | bromination | silver-induced substitution | 1,4-naphthoquinone | PCC oxidation |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 7 |
| Web of Science | 5 |