Highly brominated anthracenes as precursors for the convenient synthesis of 2 9 10 trisubstituted anthracene derivatives
Yazarlar (5)
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Dr. Öğr. Üyesi Leyla AYDOĞAN
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Atatürk Üniversitesi, Türkiye
Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
|
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Beilstein Journal of Organic Chemistry |
| Dergi ISSN | 1860-5397 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SSCI |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 12-2008 |
| Cilt No | 4 |
| Sayı | 1 |
| Sayfalar | 50 / 0 |
| DOI Numarası | 10.3762/bjoc.4.50 |
| Makale Linki | http://www.ncbi.nlm.nih.gov/pubmed/19190741 |
| Özet |
| When 9,10-dibromoanthracene was treated with bromine in CCl4 without a catalyst, 1,2,3,4,9,10-hexabromo-1,2,3,4-tetrahydroanthracene (3) was obtained in 95% yield in the absence of other stereoisomers or rearomatization products. We investigated the base-induced elimination reaction of hexabromide 3 under various conditions. Pyridine-induced elimination of hexabromide 3 afforded 2,9,10-tribromoanthracene (12) in 75% yield, and tribromide 12 was transformed to trimethoxy compound 13 and trinitrile 14 by copper-assisted nucleophilic substitution reactions. © 2008 Cakmak et al; licensee Beilstein-Institut. |
| Anahtar Kelimeler |
| Anthracene derivative | Bromination | Bromoanthracene | Cyanoanthracene | Methoxyanthracene |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 9 |