Attempted synthesis of 1 cyclohepta 1 2 dien 1 ylbenzene and Wurtz like condensation products in the reaction of 1 2 3 dibromocyclohept 1 en 1 yl benzene with zinc
Yazarlar (3)
Prof. Dr. Mustafa CEYLAN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Yakup BUDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Meliha Burcu GÜRDERE Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | TURKISH JOURNAL OF CHEMISTRY (Q4) | ||
| Dergi ISSN | 1300-0527 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2006 |
| Cilt / Sayı / Sayfa | 30 / 5 / 635–642 | DOI | – |
| Özet |
| 7, 7-Dibromo-1-phenylbicyclo [4.1. 0] heptane 4 was synthesized and its thermal and silver ion-catalyzed rearrangements were studied. Alcohol 8 was converted to 1-(2, 3-dibromocyclohept-1-en-1-yl) benzene 6. The zinc-mediated elimination of 1-(2, 3-dibromocyclohept-1-en-1-yl) benzene 6 resulted in the formation of 2 isomeric Wurtz-like condensation products 15 and 16 (whose structural assignments were based on^ 1H-and^{13} C-NMR spectral data) instead of the expected 1-cyclohepta-1, 2-dien-1-ylbenzene 14. |
| Anahtar Kelimeler |
| substituted strained cyclic allene | dehydrobomination | Wurtz-like condensation | zinc |
