Equilibrium, kinetic and thermodynamic studies of adsorption of Pb(II) from aqueous solution onto Turkish kaolinite clay
 
Yazarlar (4)
Ahmet Sarı Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Mustafa TÜZEN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Demirhan ÇITAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Mustafa Soylak Erciyes Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Hazardous Materials (Q4)
Dergi ISSN 0304-3894 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 10-2007
Kabul Tarihi 12-04-2026 Yayınlanma Tarihi
Cilt / Sayı / Sayfa 149 / 2 / 283–291 DOI 10.1016/j.jhazmat.2007.03.078
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S030438940700444X
Özet
The adsorption of Pb(II) onto Turkish (Bandırma region) kaolinite clay was examined in aqueous solution with respect to the pH, adsorbent dosage, contact time, and temperature. The linear Langmuir and Freundlich models were applied to describe equilibrium isotherms and both models fitted well. The monolayer adsorption capacity was found as 31.75mg/g at pH 5 and 20°C. Dubinin–Radushkevich (D–R) isotherm model was also applied to the equilibrium data. The mean free energy of adsorption (13.78kJ/mol) indicated that the adsorption of Pb(II) onto kaolinite clay may be carried out via chemical ion-exchange mechanism. Thermodynamic parameters, free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) of adsorption were also calculated. These parameters showed that the adsorption of Pb(II) onto kaolinite clay was feasible, spontaneous and exothermic process in nature. Furthermore, the Lagergren-first …
Anahtar Kelimeler
Adsorption isotherm | Kinetics | Pb(II) | Thermodynamics | Turkish kaolinite clay
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Google Scholar 626
Scopus 34
Web of Science 412
Equilibrium, kinetic and thermodynamic studies of adsorption of Pb(II) from aqueous solution onto Turkish kaolinite clay

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