Spectroscopic and structural properties of 2 2 dipyridylamine and its palladium and platinum complexes
Yazarlar (2)
Yurdakul Gazi Üniversitesi, Türkiye
Prof. Dr. Mustafa Tuğfan BİLKAN Gazi Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Optics and Spectroscopy English Translation of Optika I Spektroskopiya (Q4) | ||
| Dergi ISSN | 0030-400X Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2015 |
| Cilt / Sayı / Sayfa | 119 / 4 / 603–619 | DOI | 10.1134/S0030400X15100264 |
| Makale Linki | http://link.springer.com/10.1134/S0030400X15100264 | ||
| UAK Araştırma Alanları |
Sosyal, Beşeri ve Idari Bilimler
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| Özet |
| The structural features such as geometric parameters, vibration frequencies and intensities of the vibrational bands of 2,2′-dipyridylamine ligand (DPA), its palladium (Pd(DPA)Cl2) and platinum (Pt(DPA)Cl2) complexes were studied by the density functional theory (DFT). The calculations were carried out by DFT / B3LYP method with 6-311++G(d,p) and LANL2DZ basis sets. All vibrational frequencies assigned in detail with the help of total energy distribution analysis (TED). Optimized geometric bond lengths and bond angles were compared with experimental X-ray data. Using DPA, K2PtCl4, and Na2PdCl4, the synthesized complex structures were characterized by the combination of elemental analysis, FT-IR (mid and far IR) and Raman spectroscopy. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 7 |
| Google Scholar | 11 |