Biosorption of copper II lead II iron III and cobalt II on Bacillus sphaericus loaded Diaion SP 850 resin      
Yazarlar (5)
Prof. Dr. Mustafa TÜZEN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Özgür Doğan ULUÖZLÜ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Necibe Canan USTA Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Mustafa Soylak
Erciyes Üniversitesi, Türkiye
Hüsnü Dal
Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Analytica Chimica Acta
Dergi ISSN 0003-2670 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 01-2007
Cilt No 581
Sayı 2
Sayfalar 241 / 246
DOI Numarası 10.1016/j.aca.2006.08.040
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0003267006018174
Özet
The biosorption of copper(II), lead(II), iron(III) and cobalt(II) on Bacillus sphaericus-loaded Diaion SP-850 resin for preconcentration-separation of them have been investigated. The sorbed analytes on biosorbent were eluted by using 1 mol L(-1) HCl and analytes were determined by flame atomic absorption spectrometry. The influences of analytical parameters including amounts of pH, B. sphaericus, sample volume etc. on the quantitative recoveries of analytes were investigated. The effects of alkaline, earth alkaline ions and some metal ions on the retentions of the analytes on the biosorbent were also examined. Separation and preconcentration of Cu, Pb, Fe and Co ions from real samples was achieved quantitatively. The detection limits by 3 sigma for analyte ions were in the range of 0.20-0.75 microg L(-1) for aqueous samples and in the range of 2.5-9.4 ng g(-1) for solid samples. The validation of the procedure was performed by the analysis of the certified standard reference materials (NRCC-SLRS 4 Riverine Water, SRM 2711 Montana soil and GBW 07605 Tea). The presented method was applied to the determination of analyte ions in green tea, black tea, cultivated mushroom, boiled wheat, rice and soil samples with successfully results.
Anahtar Kelimeler
bacillus sphaericus | Diaion SP-850 | biosorption | preconcentration | trace metal | atomic absorption spectrometry