Development Characterization and Latent Heat Thermal Energy Storage Properties of Neopentyl Glycol Fatty Acid Esters as New Solid Liquid PCMs     
Yazarlar (3)
Ahmet Sarı
Karadeniz Teknik Üniversitesi, Türkiye
Prof. Dr. Cemil ALKAN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Alper BİÇER Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Industrial and Engineering Chemistry Research
Dergi ISSN 0888-5885 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 12-2013
Cilt No 52
Sayı 51
Sayfalar 18269 / 18275
DOI Numarası 10.1021/ie403039n
Özet
Neopentyl glycol (NPG) is known as a solid-solid phase change material (PCM) and shows a solid-solid phase transition at 41.9 C. Although it has a good latent heat capacity of 141.91 J/g, the low degradation temperature interval (80-150 C) is close to its solid-liquid phase change temperature (129.46 C), which lessens its latent heat thermal energy storage (LHTES) potential. The present study is aimed to eradicate these disadvantages by synthesizing its ester compounds with three kinds of fatty acid chlorides. The developed NPG-DL, NPG-DM, and NPG-DP esters were characterized using FT-IR and 1H NMR spectroscopy techniques. The DSC results showed that the esters had a melting point and latent heat value in the range of about 11-35 C and 98-124 J/g. The synthesized PCMs had high decomposition temperature ranges, noncorrosivity, and good odor properties. The PCMs also exhibit good thermal reliability and chemical stability besides their increased thermal conductivity. © 2013 American Chemical Society.
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