| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Energy Conversion and Management |
| Dergi ISSN | 0196-8904 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 10-2014 |
| Cilt No | 86 |
| Sayı | 1 |
| Sayfalar | 614 / 621 |
| DOI Numarası | 10.1016/j.enconman.2014.05.092 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0196890414005111 |
| Özet |
| This paper was aimed to prepare, characterize and determine the thermal energy storage properties of poly(methyl methacrylate) (PMMA)/n-nonadecane (C19) capsules as a novel micro/nanoencapsulated phase change material (M/N-EPCM). The M/N-EPCM was fabricated via emulsion polymerization reaction of methylmethacrylate (MMA) monomer occurred around C19 used as core material. The chemical structure of the prepared M/N-EPCM was verified using Fourier transform infrared (FTIR) spectroscopy method. The analysis results obtained from polarized optical microscopy (POM) and scanning electron microscopy (SEM) indicated that the synthesized micro/nanocapsules had virtually spherical shape. The particle size distribution (PSD) analysis indicated that the prepared M/N-PCM(1:2) with the highest nonadecane content had mean diameter of 8.18 μm and 4.90 (v/v%) nanosized capsules. These properties make it a feasible PCM in incorporation to thermal fluids, textile, building and food packaging materials. The differential scanning calorimetry (DSC) analysis results showed that the micro-nanoencapsulated nonadecane had a suitable melting temperature and of 31.23 °C and a total latent heat value as high as 139.20 J/g, respectively. Additionally, the prepared M/N-EPCM had good thermal durability, thermal reliability, chemical stability, phase change reversibility properties even after extended 5000 thermal cycling, and also reasonably thermal conductivity. Therefore, it had a promising potential in different thermal energy storage application such as solar thermal controlling of building envelopes, thermal protecting of vehicle battery systems, and thermal regulating applications. © 2014 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Emulsion polymerization | Latent heat | Micro/nanoencapsulated PCM | n-Nonadecane (C19) | PMMA | Thermal energy storage |
| Dergi Adı | ENERGY CONVERSION AND MANAGEMENT |
| Yayıncı | Elsevier Ltd |
| Açık Erişim | Hayır |
| ISSN | 0196-8904 |
| E-ISSN | 1879-2227 |
| CiteScore | 19,0 |
| SJR | 2,553 |
| SNIP | 2,124 |