Synthesis and characterization of two novel dicyanidoargentate I complexes containing N 2 hydroxyethyl ethylenediamine exhibiting significant biological activity
Yazarlar (3)
Bartın Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Yusuf YANAR
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | New Journal of Chemistry |
| Dergi ISSN | 1144-0546 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 10-2014 |
| Cilt No | 38 |
| Sayı | 10 |
| Sayfalar | 4760 / 4773 |
| DOI Numarası | 10.1039/c4nj00851k |
| Özet |
| Two novel cyanido-bridged bimetallic polymeric complexes, [Ni(hydeten)2Ag(CN)2] [Ag(CN)2]·H2O (C1) and [Cd2(hydeten)2Ag4(CN)8]·H2O (C2) (hydeten: N-(2-hydroxyethyl)ethylenediamine) were synthesized and characterized by elemental, FT-IR, X-ray (C2), thermal and variable temperature magnetic measurement (C1) techniques. Their anticancer, antibacterial and antifungal effects were also investigated. The crystallographic analyses showed that C2 crystallizes in the monoclinic space group P21/c and shows a 3D 6,4 ladder-type polymeric chain in which the CdII centers are linked by [Ag(CN)2]- units. The Ag⋯Ag distance exhibits a short value of 3.1365(9) Å. It features a rare linear pentameric unit of [Ag(CN)2]- ions assembled via d10-d10 interaction as building blocks. Both complexes exhibited outstanding antibacterial, antifungal and anticancer activities against ten different bacterial strains, two plant pathogenic fungi (Alternaria solani and Rhizoctonia solani) and four tumor cell lines (HT-29, HeLa, C6 and Vero), respectively. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 30 |
| SCOPUS | 31 |
| Google Scholar | 34 |