Green fluorescent protein-multi walled carbon nanotube based polymeric membrane electrode for bismuth ion detection     
Yazarlar (5)
Prof. Dr. Nihal DELİGÖNÜL Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. İlyas YILDIZ Iğdır Üniversitesi, Türkiye
Doç. Dr. Sema BİLGİN Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. İsa GÖKÇE Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Microchemical Journal
Dergi ISSN 0026-265X Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q1
Makale Dili İngilizce
Basım Tarihi 01-2023
Cilt No 190
Sayı 1
Sayfalar 7 / 0
DOI Numarası 10.1016/j.microc.2023.108710
Makale Linki http://dx.doi.org/10.1016/j.microc.2023.108710
Özet
Developing a sensor that is selective only to the target metal type remains a major challenge. Polymeric membrane electrodes are versatile devices with exceptional analytical simplicity and are frequently used in environmental analysis. A novel polymeric membrane electrode (PME) was proposed for the determination of bismuth ions with high sensitivity. In an unconventional approach, Green Fluorescent Protein (GFP) was used as an ionophore in the fabrication of PME electrodes. GFP, a member of the fluorescent protein family, has emerged as biocompatible tools, especially for biomedical applications, bioimaging, intracellular monitoring, sensors, and optical devices, and has attracted great attention thanks to its unique advantages. In this study, a high performance compatible PME has been developed by solvent casting method integrating GFP doped elastomeric multi-walled carbon nanotubes (MCNTs) into conductive plasticized polyvinyl chloride (PVC). The high metal-binding affinity of GFP made these proteins potential ionophores in the PME structure. The morphological structures of the produced GFP-doped MWCNT were characterized by HRTEM. Potentiometric behaviors and performance of the produced bismuth selective PME are summarized for both analytical and real examples. The prepared electrode exhibited Nernstian behavior with a slope of 19 ± 1 mV and a low detection limit of 4.3 × 10−6 M, and the electrode response time was observed as <40–45 s.
Anahtar Kelimeler
Polymeric Membrane Electrode | Green Fluorescent Protein | Multi-Walled Carbon Nanotube | Bismuth Ion Sensors