Synthesis, characterization, catalytic, electrochemical and thermal properties of tetradentate Schiff base complexes

DELİGÖNÜL, NİHAL; Tümer, Mehmet; Serin, Selahattin

doi:10.1007/s11243-006-0087-0

Synthesis, characterization, catalytic, electrochemical and thermal properties of tetradentate Schiff base complexes

Yazarlar (3)

Prof. Dr. Nihal DELİGÖNÜL Kahramanmaras Sütçü Imam Üniversitesi, Türkiye

Mehmet Tümer
Kahramanmaraş Sütçü İmam Üniversitesi, Türkiye

Selahattin Serin
Çukurova Üniversitesi, Türkiye

Makale Türü	Özgün Makale
Makale Alt Türü	SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı	Transition Metal Chemistry
Dergi ISSN	0340-4285 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI
Dergi Grubu	Q4
Makale Dili	İngilizce
Basım Tarihi	01-2006
Cilt No	31
Sayı	7
Sayfalar	920 / 929
DOI Numarası	10.1007/s11243-006-0087-0

Özet

In this study, the Schiff base ligands H2L¹-H 2L³ and their Cu^II, Co^II, Ni ^II, Fe^III Ru^III and VO^IV complexes have been prepared and characterized by spectroscopic and analytical techniques. All the complexes are mononuclear. Keto-enol tautomeric forms of the ligands have been investigated in polar and apolar solvents. The ligands favor the keto-form in the C7H8 and C6H14. The C-C coupling reaction of the 2,6-di-t-butylphenol has been investigated by the Co^II and Cu^II complexes. Thermal properties of the complexes have been assessed using thermal techniques and similar properties were found. In the Fe^III and Ru^III complexes, firstly, the coordinated water molecule is lost from the complex; in the second step, the chloride ion leaves the molecule in the 300-350 °C temperature range. Finally, the complexes decompose to the appropriate metal oxide at the higher temperature ranges. The electrochemical properties of the complexes have been studied in the two different solvents (DMF and CH3CN). © 2006 Springer.

Anahtar Kelimeler

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
WoS	52
SCOPUS	58
Google Scholar	94

Synthesis, characterization, catalytic, electrochemical and thermal properties of tetradentate Schiff base complexes

Dergi Adı	TRANSITION METAL CHEMISTRY
Yayıncı	Springer Netherlands
Açık Erişim	Hayır
ISSN	0340-4285
E-ISSN	1572-901X
CiteScore	3,0
SJR	0,240
SNIP	0,455

Synthesis, characterization, catalytic, electrochemical and thermal properties of tetradentate Schiff base complexes

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