Synthesis, characterization, catalytic, electrochemical and thermal properties of tetradentate Schiff base complexes
Yazarlar (3)
Prof. Dr. Nihal DELİGÖNÜL Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Mehmet Tümer Kahramanmaraş Sütçü İmam Üniversitesi, Türkiye
Selahattin Serin Çukurova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | TRANSITION METAL CHEMISTRY (Q4) | ||
| Dergi ISSN | 0340-4285 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2006 |
| Cilt / Sayı / Sayfa | 31 / 7 / 920–929 | DOI | 10.1007/s11243-006-0087-0 |
| Özet |
| In this study, the Schiff base ligands H2L1–H2L3 and their CuII, CoII, NiII, FeIII RuIII and VOIV complexes have been prepared and characterized by spectroscopic and analytical techniques. All the complexes are mononuclear. Keto-enol tautomeric forms of the ligands have been investigated in polar and apolar solvents. The ligands favor the keto-form in the C7H8 and C6H14. The C–C coupling reaction of the 2,6-di-t-butylphenol has been investigated by the CoII and CuII complexes. Thermal properties of the complexes have been assessed using thermal techniques and similar properties were found. In the FeIII and RuIII complexes, firstly, the coordinated water molecule is lost from the complex; in the second step, the chloride ion leaves the molecule in the 300–350 °C temperature range. Finally, the complexes decompose to the appropriate metal oxide at the higher temperature ranges. The electrochemical … |
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BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 96 |
| Scopus | 4 |
| Web of Science | 52 |