| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy |
| Dergi ISSN | 1386-1425 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 08-2008 |
| Cilt No | 70 |
| Sayı | 3 |
| Sayfalar | 477 / 481 |
| DOI Numarası | 10.1016/j.saa.2007.07.039 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S1386142507004209 |
| Özet |
| Crystals of the 3,3'-5,5'-tetra-tert-butyl-4,4'-diphenoquinone (TTBDQ) in the reaction mixture DCM/MeOH (1:1, v/v) were obtained as a result of CC coupling reaction of the sterically hindered phenol (2,6-di-tert-butylphenol, DTBP) using the binuclear Co(II) complexes. The oxidation product (TTBDQ), C(28)H(40)O(2), crystallizes in the space group P1 with one-half molecule in the asymmetric unit and the other half generated by an inversion centre. The diphenoquinone moiety is planar within +/-0.016(3)A. The crystal structure is stabilized by intramolecular C-H...O hydrogen bonds. The spectroscopic and electrochemical properties of the TTBDQ also have been studied. |
| Anahtar Kelimeler |
| oxidation product | X-ray | electrochemical |
| Dergi Adı | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY |
| Yayıncı | Elsevier B.V. |
| Açık Erişim | Hayır |
| ISSN | 1386-1425 |
| E-ISSN | 1873-3557 |
| CiteScore | 8,5 |
| SJR | 0,664 |
| SNIP | 1,033 |