Structural characterization and electrochemical properties of the 3 3 5 5 tetra tert butyl 4 4 diphenoquinone
Yazarlar (4)
Mehmet Tümer Kahramanmaraş Sütçü İmam Üniversitesi, Türkiye
Mehmet Aslantaş Kahramanmaraş Sütçü İmam Üniversitesi, Türkiye
Ertan Şahin Atatürk Üniversitesi, Türkiye
Prof. Dr. Nihal DELİGÖNÜL Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy (Q4) | ||
| Dergi ISSN | 1386-1425 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 08-2008 |
| Cilt / Sayı / Sayfa | 70 / 3 / 477–481 | DOI | 10.1016/j.saa.2007.07.039 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S1386142507004209 | ||
| Özet |
| Crystals of the 3,3′-5,5′-tetra-tert-butyl-4,4′-diphenoquinone (TTBDQ) in the reaction mixture DCM/MeOH (1:1, v/v) were obtained as a result of CC coupling reaction of the sterically hindered phenol (2,6-di-tert-butylphenol, DTBP) using the binuclear Co(II) complexes. The oxidation product (TTBDQ), C28H40O2, crystallizes in the space group P1¯ with one-half molecule in the asymmetric unit and the other half generated by an inversion centre. The diphenoquinone moiety is planar within ±0.016(3)Å. The crystal structure is stabilized by intramolecular CH⋯O hydrogen bonds. The spectroscopic and electrochemical properties of the TTBDQ also have been studied. |
| Anahtar Kelimeler |
| Electrochemical | Oxidation product | X-ray |
Science Direct
Structural characterization and electrochemical properties of the 3 3 5 5 tetra tert butyl 4 4 diphenoquinone
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 11 |
| Scopus | 1 |
| Web of Science | 8 |