Copper Catalyzed Huisgen 3 2 Cycloaddition of Gold I Alkynyls with Benzyl Azide Syntheses Structures and Optical Properties
Yazarlar (6)
L.L.C., Avustralya
Case Western Reserve University, Amerika Birleşik Devletleri
Massachusetts Institute Of Technology, Amerika Birleşik Devletleri
Case Western Reserve University, Amerika Birleşik Devletleri
Prof. Dr. Nihal DELİGÖNÜL
Case Western Reserve University, Amerika Birleşik Devletleri
Case Western Reserve University, Amerika Birleşik Devletleri
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Organometallics |
| Dergi ISSN | 0276-7333 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 11-2009 |
| Cilt No | 28 |
| Sayı | 21 |
| Sayfalar | 6171 / 6182 |
| DOI Numarası | 10.1021/om9005774 |
| Makale Linki | http://pubs.acs.org/doi/abs/10.1021/om9005774 |
| Özet |
| The copper(I)-catalyzed Huisgen [3 + 2] cycloaddition is a general reaction encompassing wide ranges of organoazide and primarily terminal alkyne reacting partners. Strained internal alkynes can also undergo cycloaddition with azides. We report here that tetrakis(acetonitrile)copper(I) hexafluorophosphate catalyzes the [3 + 2] cycloaddition of (phosphine)- and (N-heterocyclic carbene)gold(I) alkynyls with benzyl azide. Isolated yields of up to 96% result. The reaction protocol broadly tolerates functionalities on the alkynyl reagent. Gold(I) triazolate products form with complete 1,4-regioselectivity. Some 15 new gold(I) triazolates are reported along with crystal structures of nine. Triazolate complexes bearing polycyclic aromatic substituents show dual singlet- and triplet-state luminescence from excited states localized on the aromatic fragment. Time-resolved emission experiments find long lifetimes consistent with triplet emission parentage. Absorption and emission transitions are analyzed with time-dependent density-functional theory calculations. © 2009 American Chemical Society. |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 90 |
| SCOPUS | 92 |
| Google Scholar | 129 |