Synthesis Structures and Excited State Geometries of Alkynylgold I Complexes
Yazarlar (5)
Case Western Reserve University, Amerika Birleşik Devletleri
Llc, Amerika Birleşik Devletleri
Case Western Reserve University, Amerika Birleşik Devletleri
Prof. Dr. Nihal DELİGÖNÜL
Case Western Reserve University, Amerika Birleşik Devletleri
Case Western Reserve University, Amerika Birleşik Devletleri
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | European Journal of Inorganic Chemistry |
| Dergi ISSN | 1434-1948 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 06-2009 |
| Cilt No | 2009 |
| Sayı | 18 |
| Sayfalar | 2711 / 2719 |
| DOI Numarası | 10.1002/ejic.200900307 |
| Makale Linki | http://doi.wiley.com/10.1002/ejic.200900307 |
| Özet |
| A series of phosphane- and (N-heterocyclic carbene)gold(I) complexes were prepared by deprotonation of terminal alkyne precursors and reaction with the corresponding gold(I) chlorides. Some ten new compounds are reported; these are characterized by multinuclear NMR, optical spectroscopy, and elemental analysis. Crystallographic characterization is reported for five complexes. Organogold species bearing conjugated aryl substituents on the alkynyl ligand are luminescent. Density-functional theory calculations on a model complex suggest that emission and the first several absorption transitions result from excited states dominated by the arylacetylide ligand. Excited-state geometry optimization finds that the lowest-energy triplet state bears linear, two-coordinate gold(I) with a miniscule lengthening of the alkynyl carbon-carbon bond. An unusual triplet excited state having a bent geometry at gold lies at higher energy in arylacetylide complexes. For the model terminal acetylideMe |
| Anahtar Kelimeler |
| Gold | Alkynyl complexes | Luminescence | Triplet states | Density-functional theory |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 53 |
| SCOPUS | 56 |
| Google Scholar | 43 |
| Google Scholar | 40 |