Geminally Diaurated Aryls Bridged by Semirigid Phosphine Pillars Syntheses and Electronic Structure
Yazarlar (7)
Browne Amberle R
Case Western Reserve University
Case Western Reserve University
Prof. Dr. Nihal DELİGÖNÜL Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Anderson Bryce L
Harvard Faculty Of Arts And Sciences
Harvard Faculty Of Arts And Sciences
Rheingold Arnold L
University Of California, San Diego
University Of California, San Diego
Gray Thomas G
Case Western Reserve University
Case Western Reserve University
Murat İspiroğlu
Türkiye
Türkiye
Metin Kılınç Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chemistry - A European Journal (Q4) | ||
| Dergi ISSN | 0947-6539 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2014 |
| Cilt / Sayı / Sayfa | 20 / 52 / 17552–17564 | DOI | 10.1002/chem.201403444 |
| Makale Linki | http://doi.wiley.com/10.1002/chem.201403444 | ||
| Özet |
| Geminally diaurated μ2‐aryl complexes have been prepared where gold(I) centers were bridged by the semirigid diphosphine ligands bis(2‐diphenylphosphinophenyl)ether (DPEphos) and 4,6‐bis(diphenylphosphanyl)dibenzo[b,d]furan (DBFphos). Diaurated complexes were synthesized in ligand redistribution reactions of the corresponding di‐gold dichlorides with di‐gold diaryls (six of them new) and silver(I) salts. Diaurated complexes were isolated as salts of the minimally coordinating anions SbF6− and ReO4−. Efforts to prepare salts of the tetraarylborate [B(3,5‐(CF3)2C6H3)4]− led to transmetalation from boron, with crystallization of the fluorinated aryl complex. The new complexes were characterized by multinuclear NMR, absorption and emission spectroscopies, 77 K emission lifetimes, and by combustion analysis; three are crystallographically characterized. Structures of geminally diaurated aryl ligands … |
| Anahtar Kelimeler |
| Aromaticity | Aurophilicity | Density functional calculations | Gold | Phosphine ligands |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 23 |
| Scopus | 4 |
| Web of Science | 19 |