Synthesis of pentafluorophenyl and pyridinyl 3 allenes
Yazarlar (2)
Prof. Dr. Ramazan ERENLER Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Jean François Biellmann Academia Sinica, Institute of Chemistry, Tayvan
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of the Chinese Chemical Society (Q3) | ||
| Dergi ISSN | 0009-4536 Dergi Bilgileri (2007) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2007 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-02-2007 |
| Cilt / Sayı / Sayfa | 54 / 1 / 103–108 | DOI | 10.1002/jccs.200700017 |
| Makale Linki | https://onlinelibrary.wiley.com/doi/10.1002/jccs.200700017 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| The allenes 1,2,3,4,5‐pentafluoro‐6‐(3‐phenylpropa‐1,2‐dienyl)benzene 4, 3‐(3‐phenylpropa‐1,2‐dienyl)pyridine 11 and 3‐(3‐(pyridine‐3‐yl)propa‐1,2‐dienyl)pyridine 17 and the acetylenes 5, 12 and 16 were obtained by reduction of the corresponding propargylic acetates 3, 10 and 15 by Samarium(II) iodide in the presence of Pd(0). Base‐promoted isomerisation of acetylene 12 provided allene 11 in a yield of 80%. 1‐(Pentafluorophenyl)‐3‐phenylprop‐2‐yn‐1‐ol 2 was prepared from phenylacetylene and pentafluorobenzaldehyde. The condensation of nicotinaldehyde with trimethylsilylacetylene gave the 3‐(trimethylsilyl)‐1‐(pyridine‐3‐yl)prop‐2‐yn‐1‐ol 7. The removal of the silyl group of 7 to acetylene 8 was done in basic conditions. The Pd catalysed condensation of the acetylene 8 with iodobenzene gave 3‐phenyl‐1‐(pyridine‐3‐yl)prop‐2‐yn‐1‐ol 9. The Pd catalysed condensation of 8 with 3 … |
| Anahtar Kelimeler |
| Heterocyclic allene | Isomerisation reaction | Pyridinyl allene | Samarium diiodide | Tetrafluorophenyl allene |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Yöksis | 1 |
| Web of Science | 3 |
| Scopus | 5 |
| Google Scholar | 14 |