Facile and Efficient Bromination of Benz F Indan 1 One
Yazarlar (3)
Cihansel Sancak Unlu Sakarya Üniversitesi, Türkiye
Ahmet Tutar Sakarya Üniversitesi, Türkiye
Prof. Dr. Ramazan ERENLER Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of the Chemical Society of Pakistan | ||
| Dergi ISSN | 0253-5106 Dergi Bilgileri (2012) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2012 |
| Cilt / Sayı / Sayfa | 34 / 3 / 705–708 | DOI | – |
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| The bromination reaction of benz [f] indan-1-one was investigated by NBS, molecular bromine and fotobromination. Benz [f] indan-1-one was synthesized by treatment of (alpha),(alpha),(alpha)',(alpha)'-tetrabromo-o-xylene with cyclopenten-1-one. Bromination of benz [f] indan-1-one with bromine (1.2 equiv) at low temperature afforded the (alpha)-monobromobenz [f] indanone in addition to (alpha),(alpha)'-dibromobenz [f] indanone. The quantitative yield of (alpha),(alpha)'-dibromobenz [f] indanone was synthesized by treatment of benz [f] indan-1-one with 2.1 equv. bromine at room temperature for 25 min. The electrophonic bromination of (alpha),(alpha)'-dibromobenz [f] indanone with N-bromosuccinimide (NBS) regioselectively proceeded at C-8 side and afforded the corresponding 2, 2, 8-Tribromobenz [f] indanone which also could be obtained from the treatment of benz [f] indan-1-one with NBS and SiO2 … |
| Anahtar Kelimeler |
