A Potentiometric Sensor for the Determination of Pb(II) Ions in Different Environmental Samples
Yazarlar (4)
Doç. Dr. Oğuz ÖZBEK Zonguldak Bülent Ecevit Üniversitesi, Türkiye
Hayreddin Gezegen Cumhuriyet Üniversitesi, Türkiye
Alper Çetin Zonguldak Bulent Ecevit University, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chemistryselect (Q3) | ||
| Dergi ISSN | 2365-6549 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2022 |
| Kabul Tarihi | 18-08-2022 | Yayınlanma Tarihi | 01-09-2022 |
| Cilt / Sayı / Sayfa | 7 / 33 / 202202494–0 | DOI | 10.1002/slct.202202494 |
| Makale Linki | http://dx.doi.org/10.1002/slct.202202494 | ||
| Özet |
| In this study, a novel PVC‐based membrane containing (E)‐2‐(1‐(4‐(3‐(4‐chlorophenyl)ureido)phenyl)ethylidene)hydrazine carbothioamide (5) as an electroactive component (ionophore) along with potassium tetrakis (p‐chlorophenyl) borate (KTpClPB) and bis(2‐ethylhexyl)adipate (DEHA) in the ratio 4.0 : 32.0 : 1.0 : 63.0 (ionophore:PVC:KTpClPB:DEHA) (w/w) was used to develop a lead(II)‐selective potentiometric sensor. The sensor exhibited a Nernstian response over a wide concentration range from 1.0×10−5 to 1.0×10−1 mol L−1 with a slope of 28.0±2.0 mV/decade, and a detection limit of 1.65×10−6 mol L−1. It displayed very good selectivity towards Pb(II) ions over other cationic species. The lead(II)‐selective sensor showed a fast response time of 5 s, good repeatability, and it worked in the broad pH range of 5.0–11.0. The sensor could be used as an indicator electrode in the quantification … |
| Anahtar Kelimeler |
| Electroanalytical methods | ion-selective electrodes | ionophore | PVC membrane |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 30 |
| Scopus | 17 |