All Solid State PVC Membrane Ag Selective Electrodes Based on Diaza 18 Crown 6 Compounds
Yazarlar (6)
İbrahim Işıldak Yıldız Teknik Üniversitesi, Türkiye
Murat Yolcu Giresun Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Nadir Demirel Kırşehir Ahi Evran Üniversitesi, Türkiye
Giray Topal Dicle Üniversitesi, Türkiye
Halil Hoşgören
Dicle Üniversitesi, Türkiye
Dicle Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Microchimica Acta (Q4) | ||
| Dergi ISSN | 0026-3672 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2004 |
| Kabul Tarihi | 12-04-2026 | Yayınlanma Tarihi | 01-01-2004 |
| Cilt / Sayı / Sayfa | 144 / 1 / 177–181 | DOI | 10.1007/s00604-003-0072-7 |
| Makale Linki | http://link.springer.com/10.1007/s00604-003-0072-7 | ||
| Özet |
| Two diaza-crown ether compounds were synthesized and evaluated as Ag+-selective carriers in polyvinylchloride (PVC) membrane electrodes of solid-state type. The all-solid-state PVC membrane electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown-6 exhibited a super-Nernstian response (75±10 mV per decade) over the concentration range of 1×10−1 to 7×10−6 M of Ag+ ion and a detection limit of 3×10−6 M, at a wide range of pH (pH 4–7). The response time of the electrode was fast (less than ∼10s), and it can be used for three months without any significant deviation in potential. The proposed all-solid-state PVC membrane electrodes revealed high selectivity toward Ag+ ion with respect to alkali, alkaline earth, heavy and transition metal ions. A flow-through cell of all-solid-state PVC membrane Ag+-selective electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown-6 has also been prepared and … |
| Anahtar Kelimeler |
| All-solid-state | Diaza-crown ethers | FIA | PVC membrane | Silver-selective electrodes |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 51 |
| Scopus | 7 |