Investigation of catalytic effects of the proton and Lewis acids on oligomerization and chemical polymerization of pyrrole
Yazarlar (5)
Muzaffer Can Kırıkkale Üniversitesi, Türkiye
Hayri Özaslan Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Nuran Ö Pekmez Hacettepe Üniversitesi, Türkiye
Attila Yıldız Hacettepe Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymer (Q4)
Dergi ISSN 0032-3861 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 09-2004
Kabul Tarihi Yayınlanma Tarihi 01-09-2004
Cilt / Sayı / Sayfa 45 / 20 / 7011–7016 DOI 10.1016/j.polymer.2004.08.003
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0032386104007621
Özet
Protonation and oligomerization mechanisms of pyrrole monomer were elucidated in the presence of acid such as HBF4 and Lewis acid such as AlCl3, FeCl3 in acetonitrile solutions, using experimental methods such as UV–vis and AA spectroscopy and semi-empirical AM1 calculations. It was observed that pyrrole interacts with proton and Lewis acids on sim...
Anahtar Kelimeler
Oligomerization | Polypyrrole | Protonation