Synthesis crystal structures magnetic properties and Suzuki and Heck coupling catalytic activities of new coordination polymers containing tetracyanopalladate anions
Yazarlar (6)
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ahmet Karadağ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Yusuf Yerli Yıldız Teknik Üniversitesi, Türkiye
Nevin Gürbüz İnönü Üniversitesi, Türkiye
İsmail Özdemir İnönü Üniversitesi, Türkiye
Ertan Şahin Atatürk Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polyhedron (Q2) | ||
| Dergi ISSN | 0277-5387 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2013 |
| Cilt / Sayı / Sayfa | 49 / 1 / 50–60 | DOI | 10.1016/j.poly.2012.09.030 |
| Makale Linki | https://www.sciencedirect.com/science/article/pii/S0277538712007218 | ||
| Özet |
| Four novel coordination polymers, [Ni(bishydeten)Pd(CN)4] (1), [Cu(bishydeten)Pd(CN)4] (2), [Zn(bishydeten)Pd(CN)4] (3) and [Cd(bishydeten)Pd(CN)4] (4) (bishydeten=N,N′-bis(2-hydroxyethyl)ethylenediamine], have been synthesized and characterized by various techniques (elemental analysis, IR, EPR, X-ray and thermal analysis). In compound 4, all of the cyano groups use –N edges to form coordination bonds to Cd(II) in addition to –C atoms, resulting in the formation of a tridimensional network. The same situation is observed for compound 3 for one of the tetracyanopalladate(II) groups, while two cyano groups remain in the monodentate form coordinated to Pd(II) in the other tetracyanopalladate(II) group. While an EPR signal was not observed for 1, the g parameters obtained from the EPR spectrum of 2 indicated that the Cu(II) ions are located in tetragonal distorted octahedral sites (D4h) and that the … |
| Anahtar Kelimeler |
| Catalyst | Coordination polymers | Crystal structures | Magnetic susceptibility | Palladium complexes | Thermal analysis |
Science Direct
Synthesis crystal structures magnetic properties and Suzuki and Heck coupling catalytic activities of new coordination polymers containing tetracyanopalladate anions
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| Atıf Sayıları | |
| Google Scholar | 20 |
| Scopus | 1 |