Complexes Containing N 2 hydroxyethyl ethylenediamine with Tetracyanometallate II Synthesis IR Spectra Thermal Behavior Crystal Structure Magnetic Properties and Catalysis
Yazarlar (5)
Ahmet Karadağ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Yusuf Yerli Yıldız Teknik Üniversitesi, Türkiye
Ertan Şahin Atatürk Üniversitesi, Türkiye
Ramazan Topkaya Gebze Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials (Q4) | ||
| Dergi ISSN | 1574-1443 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2012 |
| Cilt / Sayı / Sayfa | 22 / 2 / 369–378 | DOI | 10.1007/s10904-011-9623-2 |
| Özet |
| Two novel cyano-bridged Ni2+ and Cu2+ compounds, {[M2+(hydeten)2(μ-CN)2Ni(CN)2]n, M2+ = Ni2+ (c1) and Cu2+ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, –Cu(hydeten)2-NC-Ni(CN)2-CN-Cu(hydeten)2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten)2Pd(CN)4] (c3) and [Cu(hydeten)2Pd(CN)4] (c4) [Karadağ, Z Kristallogr 222:39, ] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that Cu2+ was located in tetragonal distorted octahedral sites (D4h) and the ground state of the paramagnetic electron was \documentclass[12pt]{minimal … |
| Anahtar Kelimeler |
| Catalysis | EPR | Magnetic susceptibly | N-(2-hydroxyethyl)-ethylenediamine | Tetracyanometallate(II) | Thermal behavior |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 12 |
| Scopus | 1 |