Complexes Containing N 2 hydroxyethyl ethylenediamine with Tetracyanometallate II Synthesis IR Spectra Thermal Behavior Crystal Structure Magnetic Properties and Catalysis
Yazarlar (5)
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Yıldız Teknik Üniversitesi, Türkiye
Atatürk Üniversitesi, Türkiye
Gebze Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials |
| Dergi ISSN | 1574-1443 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 03-2012 |
| Cilt No | 22 |
| Sayı | 2 |
| Sayfalar | 369 / 378 |
| DOI Numarası | 10.1007/s10904-011-9623-2 |
| Özet |
| Two novel cyano-bridged Ni 2+ and Cu 2+ compounds, {[M 2+(hydeten) 2(μ-CN) 2Ni(CN) 2] n, M 2+= Ni 2+ (c1) and Cu 2+ (c2), N-(2-hydroxyethyl)-ethylenediamine (hydeten), were prepared and characterized by elemental analysis, IR spectroscopy and thermoanalytical measurements. The one-dimensional polymeric structure of c2, which was determined by X-ray diffraction techniques, was formed with a 2,2-TT-type chain, -Cu(hydeten) 2-NC-Ni(CN) 2-CN-Cu(hydeten) 2-, linkages. Also, while the EPR spectra and magnetic properties of complexes c1 and c2 with [Ni(hydeten) 2Pd(CN) 4] (c3) and [Cu(hydeten) 2Pd(CN) 4] (c4) [Karadaǧ, Z Kristallogr 222:39, 2007] were investigated, the catalytic activity of c3 and c4 was studied. The EPR spectra of c2 and c4 showed that Cu 2+ was located in tetragonal distorted octahedral sites (D 4h) and the ground state of the paramagnetic electron was d x2-y2. The magnetic behavior exhibited weak antiferromagnetic interactions in all the complexes. Also, the catalytic properties of c3 and c4, which were assigned with Suzuki and Heck coupling reactions, showed that they did not have catalytic effects. © 2012 Springer Science+Business Media, LLC. |
| Anahtar Kelimeler |
| Catalysis | EPR | Magnetic susceptibly | N-(2-hydroxyethyl)-ethylenediamine | Tetracyanometallate(II) | Thermal behavior |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 12 |
| Google Scholar | 11 |