Synthesis and Characterization of New Metal Organic Frameworks Based on Tetracyanoplatinate II and N N bis 2 hydroxyethyl ethylenediamine Single Crystal Structures of Zn II and Cd II Complexes Along with Magnetic Properties of Ni II and Cu II Complexes
Yazarlar (4)
Doç. Dr. Ayşegül ŞENOCAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Atatürk Üniversitesi, Türkiye
Yıldız Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials |
| Dergi ISSN | 1574-1443 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2011 |
| Cilt No | 21 |
| Sayı | 3 |
| Sayfalar | 438 / 449 |
| DOI Numarası | 10.1007/s10904-011-9466-x |
| Özet |
| Characterization and synthesis of novel cyano bridged coordination compounds [Ni(bishydeten)Pt(CN) 4 ] (1), [Cu(bishydeten)Pt(CN) 4 ] (2), [Zn(bishydeten)Pt(CN) 4 ] (3), [Cd(bishydeten)Pt(CN) 4 ] (4) [bishydeten = N,N′-bis(2-hydroxyethyl)ethylenediamine (C 6 H 16 N 2 O 2 )] were reported herein. The IR spectra of these coordination compounds verified the formation of aforementioned complexes. The ground state of the paramagnetic electron in the Cu II located in tetragonal distorted octahedral sites (D 4h ) was found to be d x2-y2 for complex 2. As for complex 1, an EPR signal was not observed because of diamagnetic property of the Pt II and momentary relaxation times of the Ni II . All complexes followed identical decomposition mechanism in thermal analysis and thermal stabilities of complexes changed in the order of 1 > 4 > 3 > 2. Both 3 and 4 exhibit polymeric structure according to X-ray single structure analysis. While bishydeten coordinated with three donor atoms (N,N′, and O) in complex 3, it acts as a bidentate ligand (N, and N′) in complex 4. Magnetic properties of complexes 1-2 at 15-300 K temperature range were determined as antiferromagnetic with Weiss constants = -2. 619 and -0. 847 K respectively. © 2011 Springer Science+Business Media, LLC. |
| Anahtar Kelimeler |
| Cyano bridged polymers | EPR | Magnetic susceptibility | N,N′-bis(2-hydroxyethyl)ethylenediamine | Thermal analysis |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 13 |