Synthesis and Characterization of New Metal Organic Frameworks Based on Tetracyanoplatinate II and N N bis 2 hydroxyethyl ethylenediamine Single Crystal Structures of Zn II and Cd II Complexes Along with Magnetic Properties of Ni II and Cu II Complexes
Yazarlar (4)
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ahmet Karadağ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ertan Şahin Atatürk Üniversitesi, Türkiye
Yusuf Yerli Yıldız Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials (Q4) | ||
| Dergi ISSN | 1574-1443 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2011 |
| Cilt / Sayı / Sayfa | 21 / 3 / 438–449 | DOI | 10.1007/s10904-011-9466-x |
| Özet |
| Characterization and synthesis of novel cyano bridged coordination compounds [Ni(bishydeten)Pt(CN)4] (1), [Cu(bishydeten)Pt(CN)4] (2), [Zn(bishydeten)Pt(CN)4] (3), [Cd(bishydeten)Pt(CN)4] (4) [bishydeten = N,N′-bis(2-hydroxyethyl)ethylenediamine (C6H16N2O2)] were reported herein. The IR spectra of these coordination compounds verified the formation of aforementioned complexes. The ground state of the paramagnetic electron in the CuII located in tetragonal distorted octahedral sites (D4h) was found to be dx2−y2 for complex 2. As for complex 1, an EPR signal was not observed because of diamagnetic property of the PtII and momentary relaxation times of the NiII. All complexes followed identical decomposition mechanism in thermal analysis and thermal stabilities of complexes changed in the order of 1 > 4 > 3 > 2. Both 3 and 4 exhibit polymeric structure according to X-ray single structure analysis … |
| Anahtar Kelimeler |
| Cyano bridged polymers | EPR | Magnetic susceptibility | N,N′-bis(2-hydroxyethyl)ethylenediamine | Thermal analysis |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 12 |
| Scopus | 1 |