Two Novel Bimetallic Cyano Bridged Coordination Polymers Containing the 2 2 Ethylenedioxy bis Ethylamine Syntheses Structural Thermal and Magnetic Properties
Yazarlar (5)
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ahmet Karadağ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Yusuf Yerli Yıldız Teknik Üniversitesi, Türkiye
Ömer Andaç Ondokuz Mayıs Üniversitesi, Türkiye
Ertan Şahin Atatürk Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials (Q4) | ||
| Dergi ISSN | 1574-1443 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2010 |
| Cilt / Sayı / Sayfa | 20 / 4 / 628–635 | DOI | 10.1007/s10904-010-9361-x |
| Özet |
| Two new cyano bridged bimetallic polymeric complexes, [Ni(edbea)Ni(CN)4]·1/2H2O (1) and [Cu(μ-edbea)(μ-CN)2 Ni(CN)2]·H2O (2) [edbea = 2,2′-(ethylenedioxy)bis(ethylamine)] have been synthesized by adding metal chloride (M = NiII and CuII), and edbea into [Ni(CN)4]2− in water–ethanol solution and then characterized by elemental analysis, infrared (IR) and electron paramagnetic resonance (EPR) (for only complex 2) spectra, variable temperature magnetic measurement, and thermal gravimetric analysis. The X-ray diffraction crystal structure of complex 2 shows a 2D polymeric chain –edbea(N5,O1)–Cu1–N1C1–Ni(CN)2–C4N6–Cu1–(N6,O2) edbea– in which the CuII centers are linked by two cyano and one edbea. The powder EPR spectrum of the complex 2 has shown that CuII ions are located in rhombically distorted octahedral sites. The magnetic properties of the coordination polymers have been … |
| Anahtar Kelimeler |
| 2,2′-(Ethylenedioxy)bis(ethylamine) | Cyano-bridged polymeric complexes | Magnetic properties | Tetracyanonickellate | Thermal analysis |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 13 |