Two Novel Bimetallic Cyano Bridged Coordination Polymers Containing the 2 2 Ethylenedioxy bis Ethylamine Syntheses Structural Thermal and Magnetic Properties
Yazarlar (5)
Doç. Dr. Ayşegül ŞENOCAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Yıldız Teknik Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
Atatürk Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Inorganic and Organometallic Polymers and Materials |
| Dergi ISSN | 1574-1443 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 12-2010 |
| Cilt No | 20 |
| Sayı | 4 |
| Sayfalar | 628 / 635 |
| DOI Numarası | 10.1007/s10904-010-9361-x |
| Özet |
| Two new cyano bridged bimetallic polymeric complexes, [Ni(edbea)Ni(CN) 4]·1/2H 2O (1) and [Cu(μ-edbea)(μ-CN) 2 Ni(CN) 2]·H 2O (2) [edbea = 2,2′-(ethylenedioxy)bis(ethylamine)] have been synthesized by adding metal chloride (M = Ni II and Cu II), and edbea into [Ni(CN) 4] 2- in water-ethanol solution and then characterized by elemental analysis, infrared (IR) and electron paramagnetic resonance (EPR) (for only complex 2) spectra, variable temperature magnetic measurement, and thermal gravimetric analysis. The X-ray diffraction crystal structure of complex 2 shows a 2D polymeric chain -edbea(N5,O1)-Cu1-N1C1-Ni(CN)2-C4N6-Cu1-(N6,O2) edbea- in which the Cu II centers are linked by two cyano and one edbea. The powder EPR spectrum of the complex 2 has shown that Cu II ions are located in rhombically distorted octahedral sites. The magnetic properties of the coordination polymers have been studied in temperature range of 15-300 K. The magnetic behaviors investigation of complexes 1 and 2 indicated the presence of a very weak antiferromagnetic interaction. © 2010 Springer Science+Business Media, LLC. |
| Anahtar Kelimeler |
| 2,2′-(Ethylenedioxy)bis(ethylamine) | Cyano-bridged polymeric complexes | Magnetic properties | Tetracyanonickellate | Thermal analysis |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 14 |
| Google Scholar | 14 |