Syntheses IR spectra thermal properties and crystal structures of novel cyano bridged polymeric complexes of zincII and cadmiumII with tetracyanoplatinateII     
Yazarlar (6)
Ahmet Karadağ
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
İbrahim Önal
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
İbrahim Uçar
Ondokuz Mayıs Üniversitesi, Türkiye
Ahmet Bulut
Ondokuz Mayıs Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Polyhedron
Dergi ISSN 0277-5387 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q2
Makale Dili İngilizce
Basım Tarihi 01-2008
Cilt No 27
Sayı 1
Sayfalar 223 / 231
DOI Numarası 10.1016/j.poly.2007.09.016
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0277538707005797
Özet
Two novel one-dimensional polymeric cyano-bridged platinum(II) complexes of N-(2-hydroxyethyl)-ethylenediamine (hydeten), [MII(hydeten)Pt(CN)2(μ-CN)2]n (MII = ZnII (1) and CdII (2)), were synthesized and characterized by physico-chemical methods (elemental analysis, IR spectroscopy and thermoanalytical measurements) and X-ray diffraction. Thermal behaviours of 1 and 2 were followed using TG and DTA (DSC) techniques. The 1D chain structures of 1 and 2 were verified by X-ray diffraction studies. According to the positions of the bridging cyano groups, in complex 1 the polymeric chains are built up via the 2,2-CT type, while in complex 2 the polymeric chains are built up via the 2,2-TT type. © 2007 Elsevier Ltd. All rights reserved.
Anahtar Kelimeler
Cadmium | Coordination polymers | N-(2-Hydroxyethyl)-ethylenediamine | Tetracyanoplatinate(II) | Zinc