Syntheses IR spectra thermal properties and crystal structures of novel cyano bridged polymeric complexes of zincII and cadmiumII with tetracyanoplatinateII
  
Yazarlar (6)
Ahmet Karadağ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
İbrahim Önal
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
İbrahim Uçar
Ondokuz Mayıs Üniversitesi, Türkiye
Ahmet Bulut Ondokuz Mayıs Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polyhedron (Q2)
Dergi ISSN 0277-5387 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2008
Cilt / Sayı / Sayfa 27 / 1 / 223–231 DOI 10.1016/j.poly.2007.09.016
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0277538707005797
Özet
Two novel one-dimensional polymeric cyano-bridged platinum(II) complexes of N-(2-hydroxyethyl)-ethylenediamine (hydeten), [MII(hydeten)Pt(CN)2(μ-CN)2]n (MII=ZnII (1) and CdII (2)), were synthesized and characterized by physico-chemical methods (elemental analysis, IR spectroscopy and thermoanalytical measurements) and X-ray diffraction. Thermal behaviours of 1 and 2 were followed using TG and DTA (DSC) techniques. The 1D chain structures of 1 and 2 were verified by X-ray diffraction studies. According to the positions of the bridging cyano groups, in complex 1 the polymeric chains are built up via the 2,2-CT type, while in complex 2 the polymeric chains are built up via the 2,2-TT type.
Anahtar Kelimeler
Cadmium | Coordination polymers | N-(2-Hydroxyethyl)-ethylenediamine | Tetracyanoplatinate(II) | Zinc