Preparation structural magnetic and thermal properties of two heterobimetallic cyano bridged nickel II copper II platinum II coordination polymers
Yazarlar (6)
Ahmet Karadaǧ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ibrahim Önal
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Yusuf Yerli Gebze Teknik Üniversitesi, Türkiye
Ertan Şahin Atatürk Üniversitesi, Türkiye
A. Cemil Başaran
Gebze Teknik Üniversitesi, Türkiye
Gebze Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Inorganica Chimica Acta (Q4) | ||
| Dergi ISSN | 0020-1693 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2009 |
| Cilt / Sayı / Sayfa | 362 / 7 / 2299–2304 | DOI | 10.1016/j.ica.2008.10.020 |
| Özet |
| Two unique bimetalic Pt(II) coordination polymers of composition [Ni(hydeten)2Pt(CN)4] (Ni–Pt) and [Cu(hydeten)2Pt(CN)4] (Cu–Pt) [hydeten=N-(2-hydroxyethyl-ethylenediamine) or 2-(2-aminoethylamino)ethanol] have been synthesized and structurally characterized by various methods in this study. The crystal structure of Cu–Pt was determined by single-crystal X-ray diffraction analysis. The structure of Cu–Pt forms of infinite 2,2-TT type [–Cu(hydeten)2–NC–Pt(CN)2–CN–] chains containing paramagnetic copper atoms bridged by tetracyanoplatinate species. In this complex, Cu(II) centers display an axially elongated octahedron with two chelating hydeten molecules in the equatorial positions and N-bonded bridging cyano groups in the axial positions, whereas Pt(II) centers are four coordinate with four cyanide-carbon atoms in a square-planar arrangement. The decrease of the moments of these complexes in … |
| Anahtar Kelimeler |
| Copper(II) | Cyano-bridged complexes | Magnetic properties | Nickel(II) | Platinum(II) | Thermal analysis |
Science Direct
Preparation structural magnetic and thermal properties of two heterobimetallic cyano bridged nickel II copper II platinum II coordination polymers
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 28 |