Preparation structural magnetic and thermal properties of two heterobimetallic cyano bridged nickel II copper II platinum II coordination polymers
Yazarlar (6)
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Gebze Teknik Üniversitesi, Türkiye
Atatürk Üniversitesi, Türkiye
Gebze Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Inorganica Chimica Acta |
| Dergi ISSN | 0020-1693 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 05-2009 |
| Cilt No | 362 |
| Sayı | 7 |
| Sayfalar | 2299 / 2304 |
| DOI Numarası | 10.1016/j.ica.2008.10.020 |
| Özet |
| Two unique bimetalic Pt(II) coordination polymers of composition [Ni(hydeten)2Pt(CN)4] (Ni-Pt) and [Cu(hydeten)2Pt(CN)4] (Cu-Pt) [hydeten = N-(2-hydroxyethyl-ethylenediamine) or 2-(2-aminoethylamino)ethanol] have been synthesized and structurally characterized by various methods in this study. The crystal structure of Cu-Pt was determined by single-crystal X-ray diffraction analysis. The structure of Cu-Pt forms of infinite 2,2-TT type [-Cu(hydeten)2-NC-Pt(CN)2-CN-] chains containing paramagnetic copper atoms bridged by tetracyanoplatinate species. In this complex, Cu(II) centers display an axially elongated octahedron with two chelating hydeten molecules in the equatorial positions and N-bonded bridging cyano groups in the axial positions, whereas Pt(II) centers are four coordinate with four cyanide-carbon atoms in a square-planar arrangement. The decrease of the moments of these complexes in temperature range of 50 305 K can assigned to the antiferromagnetic interactions in the structures. The thermal decomposition of Cu-Pt comprise of five distinguished stages, while the thermal decomposition of Ni-Pt take place four different stages. © 2008 Elsevier B.V. All rights reserved. |
| Anahtar Kelimeler |
| Copper(II) | Cyano-bridged complexes | Magnetic properties | Nickel(II) | Platinum(II) | Thermal analysis |
Science Direct
Preparation structural magnetic and thermal properties of two heterobimetallic cyano bridged nickel II copper II platinum II coordination polymers
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 26 |
| Google Scholar | 29 |