Preparations IR spectra and crystal structures of cyano bridged bimetallic complexes of zinc II and cadmium II with tetracyanopalladate II
Yazarlar (5)
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
Doç. Dr. Ayşegül ŞENOCAK
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Journal of Coordination Chemistry |
| Dergi ISSN | 0095-8972 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 08-2007 |
| Cilt No | 60 |
| Sayı | 19 |
| Sayfalar | 2035 / 2044 |
| DOI Numarası | 10.1080/00958970701236701 |
| Özet |
| The novel heteronuclear compounds [Zn(hydet-en)2Pd(CN)4] (1) and [Cd(hydet-en)2Pd(CN)4] (2) {hydet-en: N-(2-hydroxyethyl-ethylenediamine)} have been synthesized and characterized by elemental analyses and IR spectra. The crystal structures of 1 and 2 have been determined by X-ray diffraction. Structural analysis shows that both compounds have shown a polymeric chain, in which the Zn(II)/Pd(II) and Cd(II)/Pd(II) centres are linked by two CN groups. Both zinc and cadmium atoms are six coordinate with two trans cyanide-nitrogen and four hydet-en N atoms in a distorted octahedron arrangement; the palladium atoms in 1 and 2 are four coordinate with four cyanide-C atoms in a square planar arrangement. The chains in both compounds are connected through weak interchain hydrogen bonds, N-H ⋯ O, N-H ⋯ N and O-H ⋯ N, thereby forming a three-dimensional network. © 2007 Taylor & Francis. |
| Anahtar Kelimeler |
| Crystal structures | Cyano-bridged complexes | Heteronuclear Pd complexes | Polymeric chains |
Science Direct
Preparations IR spectra and crystal structures of cyano bridged bimetallic complexes of zinc II and cadmium II with tetracyanopalladate II
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 32 |
| Google Scholar | 33 |