Palladium complexes of NO type Schiff bases: synthesis, characterization and antioxidant activities      
Yazarlar (2)
Doç. Dr. Ayşegül ŞENOCAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Hüseyin AKBAŞ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale
Makale Alt Türü Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayınlanan tam makale
Dergi Adı Cumhuriyet Science Journal
Dergi ISSN 2587-2680
Dergi Tarandığı Indeksler TR DİZİN
Makale Dili İngilizce
Basım Tarihi 03-2021
Cilt No 42
Sayı 1
Sayfalar 68 / 74
DOI Numarası 10.17776/csj.824566
Makale Linki http://dx.doi.org/10.17776/csj.824566
Özet
The reaction of o-aminophenol with para hydroxy and methoxy substituted benzaldehydes yielded two Schiff bases. These Schiff bases functioning precursors were turned into palladium complexes by treating palladium acetate. The structural formulas based on spectral methods (elemental analysis, FT-IR spectroscopy, NMR spectroscopy and QTOF- LC/MS spectroscopy) were suggested for obtained both complexes. According to the structural characterization methods, one of the complexes had also an acetate co-ligand along with the hydroxy substituted Schiff base ligand. In the other complex, the palladium central ion was proposed to be coordinated with two methoxy substituted Schiff bases. Besides, DPPH scavenging activities of the all synthesized compounds were determined and compared to well-known antioxidant standards. According to the results, antioxidant activities of the palladium complexes was mild but lower than parent Schiff bases.
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