Protic Ionic Liquid Based Potentiometric Sensors: High Selectivity Detection of Silver(I) Ions
Yazarlar (4)
Abdulkadir Akyasan
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Oğuz ÖZBEK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Hüseyin AKBAŞ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Chemistryselect (Q3) | ||
| Dergi ISSN | 2365-6549 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2025 |
| Cilt / Sayı / Sayfa | 10 / 3 / – | DOI | 10.1002/slct.202405507 |
| Makale Linki | https://doi.org/10.1002/slct.202405507 | ||
| UAK Araştırma Alanları |
Analitik Kimya
Elektrokimya
Spektroskopi
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| Özet |
| Protic ionic liquids or protic molten salts (PILs or PMOSs) consist entirely of ions and can undergo almost unlimited structural changes. ILs have been extensively used in the field of electroanalysis due to their high electrochemical stability and ionic conductivity. In this study, the usability of a PMOS as an ionophore was investigated. Firstly, 2‐phenylethylammonium benzoate (2PEAB) was synthesized, and then polymer membrane sensors containing this ionophore were prepared. The prepared sensors exhibited very high selectivity towards silver(I) ions. The novel silver(I)‐selective potentiometric sensor had a wide linear working range over the concentration range of 1.0 × 10−1–1.0 × 10−5 M, a low detection limit of 7.14 × 10−6 M, and Nernstian response of 59.3 ± 3.7 mV/decade. The prepared sensors had a relatively fast response time of <7 s, good reproducibility and a wide pH working range (4.0–10.0). The … |
| Anahtar Kelimeler |
| Ionic liquid | Potentiometry | Salt | Sensor | Silver(I) |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 15 |
| Google Scholar | 15 |