Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material  
Yazarlar (2)
Doç. Dr. Oğuz ÖZBEK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Mehmet Alperen Şahin
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayınlanan tam makale
Dergi Adı Resources Chemicals and Materials
Dergi ISSN 2772-4433 Scopus Dergi
Makale Dili İngilizce
Basım Tarihi 03-2025
Cilt No 4
Sayı 1
DOI Numarası 10.1016/j.recm.2024.07.003
Makale Linki https://doi.org/10.1016/j.recm.2024.07.003
Özet
Potassium is one of the macro minerals necessary for the cellular functions, obtained from foods. Excessive amounts of potassium can cause health problems. Determination of potassium in various samples, especially food and drug samples, is an important task. In this study, we developed a new potentiometric sensor selective to potassium ions. The sensor had a detection limit of 8.64 × 10-5 M in the concentration range of 1.0 × 10-1–1.0 × 10-4 M and a near–Nernstian behavior of 49.0 ± 4.32 mV/decade. The sensor exhibited a response time of 10 s, as well as good selectivity, good repeatability, and a wide pH working range (4.0–11.0). The developed sensor was successfully applied to a drug sample and different water samples with very high recoveries (>91.20 %).
Anahtar Kelimeler
Electroanalytical methods | Ion–selective sensor | Potassium | Potentiometry