Highly selective potentiometric detection of arsenate ions based on a newly synthesized protic alkanolammonium ionic liquid
Yazarlar (4)
Onur Cem Altuoluk
Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Doç. Dr. Oğuz ÖZBEK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Hüseyin AKBAŞ Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Prof. Dr. Ömer IŞILDAK Tokat Gaziosmanpaşa Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Microchemical Journal (Q1)
Dergi ISSN 0026-265X Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 06-2025
Cilt / Sayı / Sayfa 213 / 1 / – DOI 10.1016/j.microc.2025.113784
Makale Linki https://doi.org/10.1016/j.microc.2025.113784
UAK Araştırma Alanları
Analitik Kimya Elektrokimya Spektroskopi
Özet
In this study, an all–solid–state electrochemical sensor based on a newly synthesized protic alkanolammonium ionic liquid (TEAC3C) was developed and reported for the highly selective and sensitive potentiometric determination of arsenate ions. After the characterization of the newly synthesized ionic liquid was performed by 1H–, 13C– NMR, FT–IR, and DSC spectroscopic methods, all–solid–state polymer membrane sensors were prepared using this molecule as an electroactive material. The developed arsenate–selective potentiometric sensor had a wide linear working range of 1.0 × 10−3–1.0 × 10−8 M (R2 = 0.9967) and a low detection limit of 9.61 × 10−9 M. It also showed good potentiometric performance in terms of selectivity, reproducibility, response time (∼8s), and pH range (4.0–9.0). The surface characterization of the sensor with optimum working conditions was carried out by scanning electron …
Anahtar Kelimeler
Arsenate | Ionic liquid | Potentiometry | Sensor